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- W2073624198 startingPage "1108" @default.
- W2073624198 abstract "Sulfenamides were found to react readily with soft nucleophiles in the presence of active hydrogen compounds. A new method for the synthesis of carboxamide from metal carboxylate, sulfenamide and tertiary phosphine was developed. The effects of metal component were examined. Copper(II) salts gave the best result. In a similar way, peptides were synthesized by the reaction of copper(II) salts of acylamino acid, or free acylamino acid in the presence of cupric chloride and triethylamine, with NPS-amino acid derivatives and triphenylphosphine. When organo-mercuric compounds such as dianisylmercury were used in place of cupric chloride and triethylamine in the above reaction, almost complete retention of configuration was observed by the Young test." @default.
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- W2073624198 date "1971-04-01" @default.
- W2073624198 modified "2023-10-17" @default.
- W2073624198 title "Peptide Synthesis by Oxidation-Reduction Condensation. I. Use of NPS-Peptides as Amino Component" @default.
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- W2073624198 doi "https://doi.org/10.1246/bcsj.44.1108" @default.
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