Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073637122> ?p ?o ?g. }
Showing items 1 to 51 of
51
with 100 items per page.
- W2073637122 abstract "Manganese monophosphide and other first row transition metal phosphides have been studied by x-ray photoelectron spectroscopy in collaboration with colleagues at Ames Laboratory. Electron binding energies of both valence-conduction band and core level electrons show an evolution of metallic behavior in the series ScP, TiP, VP, MnP, FeP, and in the series FeP, Fe/sub 2/P, Fe/sub 3/P. Phosphorus dissociation pressure measurements on MnP lead to: 4MnP/sub (s)/ = 2Mn/sub 2/P/sub (s)/ + P/sub 2//sub (g)/, ..delta..H/sup 0//sub 298/ /sub 15//sub R/ = 35.1 +- 1.0 kK when the data are treated by the third law method using estimated entropies. Combination of this result with published data yields: ..delta..H/sup 0//sub f/ /sub 298/ /sub 15/(MnP) = -12.5 +- 0.6 kK which is in satisfactory agreement with the published value: ..delta..H/sup 0//sub f/ /sub 298/ /sub 15/ = -11.6 kK. The apparently low value of the atomization enthalpy of MnP is confirmed and is attributed to a high valence state preparation energy. A study of the congruent vaporization of Mn/sub 2/P has been initiated. Apparatus for solid state galvanic cell measurements on metal phosphide systems has been fabricated and assembled. Studies are proceeding on a high pressure synthesis of MnP/sub 3/." @default.
- W2073637122 created "2016-06-24" @default.
- W2073637122 creator A5020901095 @default.
- W2073637122 creator A5036865681 @default.
- W2073637122 creator A5048824152 @default.
- W2073637122 creator A5069748897 @default.
- W2073637122 creator A5089760542 @default.
- W2073637122 date "1980-03-01" @default.
- W2073637122 modified "2023-09-27" @default.
- W2073637122 title "Energies and bonding in manganese phosphides. Annual progress report, July 1, 1979-June 30, 1980" @default.
- W2073637122 doi "https://doi.org/10.2172/5313737" @default.
- W2073637122 hasPublicationYear "1980" @default.
- W2073637122 type Work @default.
- W2073637122 sameAs 2073637122 @default.
- W2073637122 citedByCount "0" @default.
- W2073637122 crossrefType "report" @default.
- W2073637122 hasAuthorship W2073637122A5020901095 @default.
- W2073637122 hasAuthorship W2073637122A5036865681 @default.
- W2073637122 hasAuthorship W2073637122A5048824152 @default.
- W2073637122 hasAuthorship W2073637122A5069748897 @default.
- W2073637122 hasAuthorship W2073637122A5089760542 @default.
- W2073637122 hasBestOaLocation W20736371223 @default.
- W2073637122 hasConcept C191897082 @default.
- W2073637122 hasConcept C192562407 @default.
- W2073637122 hasConcept C39432304 @default.
- W2073637122 hasConcept C528890316 @default.
- W2073637122 hasConceptScore W2073637122C191897082 @default.
- W2073637122 hasConceptScore W2073637122C192562407 @default.
- W2073637122 hasConceptScore W2073637122C39432304 @default.
- W2073637122 hasConceptScore W2073637122C528890316 @default.
- W2073637122 hasLocation W20736371221 @default.
- W2073637122 hasLocation W20736371222 @default.
- W2073637122 hasLocation W20736371223 @default.
- W2073637122 hasLocation W20736371224 @default.
- W2073637122 hasLocation W20736371225 @default.
- W2073637122 hasOpenAccess W2073637122 @default.
- W2073637122 hasPrimaryLocation W20736371221 @default.
- W2073637122 hasRelatedWork W164397956 @default.
- W2073637122 hasRelatedWork W2022507789 @default.
- W2073637122 hasRelatedWork W2322722469 @default.
- W2073637122 hasRelatedWork W2617332963 @default.
- W2073637122 hasRelatedWork W2899084033 @default.
- W2073637122 hasRelatedWork W2910157041 @default.
- W2073637122 hasRelatedWork W3046190049 @default.
- W2073637122 hasRelatedWork W4236062241 @default.
- W2073637122 hasRelatedWork W4252751901 @default.
- W2073637122 hasRelatedWork W4253328832 @default.
- W2073637122 isParatext "false" @default.
- W2073637122 isRetracted "false" @default.
- W2073637122 magId "2073637122" @default.
- W2073637122 workType "report" @default.