FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073639876> ?p ?o ?g. }

• W2073639876 endingPage "48" @default.
• W2073639876 startingPage "40" @default.
• W2073639876 abstract "We measured the Fe isotope fractionation during the reactions of Fe(II) with goethite in the presence and absence of a strong Fe(III) chelator (desferrioxamine mesylate, DFAM). All experiments were completed in an O2-free glove box. The concentrations of aqueous Fe(II) ([Fe(II)aq]) decreased below the initial total dissolved Fe concentrations ([Fe(II)total], 2.15 mM) due to fast adsorption within 0.2 day. The concentration of adsorbed Fe(II) ([Fe(II)ads]) was determined as the difference between [Fe(II)aq] and the concentration of extracted Fe(II) in 0.5 M HCl ([Fe(II)extr]) (i.e., [Fe(II)ads] = [Fe(II)extr] − [Fe(II)aq]). [Fe(II)ads] also decreased with time in experiments with and without DFAM, documenting that fast adsorption was accompanied by a second, slower reaction. Interestingly, [Fe(II)extr] was always smaller than [Fe(II)total], indicating that some Fe(II) was sequestered into a pool that is not HCl-extractable. The difference was attributed to Fe(II) incorporated into goethite structure (i.e., [Fe(II)inc] = [Fe(II)total] −[Fe(II)extr]). More Fe(II) was incorporated in the presence of DFAM than in its absence at all time steps. Regardless of the presence of DFAM, both aqueous and extracted Fe(II) (δ56/54Fe(II)aq and δ56/54Fe(II)extr) became isotopically lighter than or similar to goethite (− 0.27‰) at day 7, implying that the isotope exchange occurred between bulk goethite and aqueous Fe. Consistently, the mass balance indicated that the incorporated Fe is isotopically heavier than extracted Fe. These observations suggested that (i) co-adsorption of Fe(II) with DFAM resulted in more pervasive electron transfer, (ii) the electron transfer from heavy Fe(II) in the adsorbed Fe(II) to light Fe(III) in goethite results in the fixation of heavy adsorbed Fe(III) on the surface and accumulation of Fe(II) within the goethite, and (iii) desorption of the reduced, light Fe from goethite does not necessarily occur at the same surface sites where adsorption occurred." @default.
• W2073639876 created "2016-06-24" @default.
• W2073639876 creator A5012376229 @default.
• W2073639876 creator A5017211359 @default.
• W2073639876 creator A5059226320 @default.
• W2073639876 creator A5072460133 @default.
• W2073639876 creator A5080101155 @default.
• W2073639876 date "2008-05-01" @default.
• W2073639876 modified "2023-09-24" @default.
• W2073639876 title "An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite" @default.
• W2073639876 cites W1663486806 @default.
• W2073639876 cites W1967199319 @default.
• W2073639876 cites W1969594792 @default.
• W2073639876 cites W1975665084 @default.
• W2073639876 cites W1979519515 @default.
• W2073639876 cites W1979621561 @default.
• W2073639876 cites W1984854172 @default.
• W2073639876 cites W1986869433 @default.
• W2073639876 cites W1987478315 @default.
• W2073639876 cites W1987716298 @default.
• W2073639876 cites W1990404359 @default.
• W2073639876 cites W1992615119 @default.
• W2073639876 cites W1999441767 @default.
• W2073639876 cites W2004200788 @default.
• W2073639876 cites W2006223922 @default.
• W2073639876 cites W2012948404 @default.
• W2073639876 cites W2013351001 @default.
• W2073639876 cites W2020817981 @default.
• W2073639876 cites W2021289303 @default.
• W2073639876 cites W2024627840 @default.
• W2073639876 cites W2024731134 @default.
• W2073639876 cites W2030640705 @default.
• W2073639876 cites W2031332048 @default.
• W2073639876 cites W2045009168 @default.
• W2073639876 cites W2046359620 @default.
• W2073639876 cites W2052099565 @default.
• W2073639876 cites W2053561848 @default.
• W2073639876 cites W2057980421 @default.
• W2073639876 cites W2061338944 @default.
• W2073639876 cites W2066340240 @default.
• W2073639876 cites W2070912856 @default.
• W2073639876 cites W2071704543 @default.
• W2073639876 cites W2074797379 @default.
• W2073639876 cites W2077370495 @default.
• W2073639876 cites W2077683500 @default.
• W2073639876 cites W2078688410 @default.
• W2073639876 cites W2078992117 @default.
• W2073639876 cites W2079103707 @default.
• W2073639876 cites W2086373249 @default.
• W2073639876 cites W2089556823 @default.
• W2073639876 cites W2091913250 @default.
• W2073639876 cites W2092451240 @default.
• W2073639876 cites W2095145136 @default.
• W2073639876 cites W2102484660 @default.
• W2073639876 cites W2119609041 @default.
• W2073639876 cites W2128185490 @default.
• W2073639876 cites W2133266834 @default.
• W2073639876 cites W2137340366 @default.
• W2073639876 cites W2139633475 @default.
• W2073639876 cites W2150451544 @default.
• W2073639876 cites W2154836565 @default.
• W2073639876 cites W2165888175 @default.
• W2073639876 cites W4236010733 @default.
• W2073639876 doi "https://doi.org/10.1016/j.chemgeo.2008.02.002" @default.
• W2073639876 hasPublicationYear "2008" @default.
• W2073639876 type Work @default.
• W2073639876 sameAs 2073639876 @default.
• W2073639876 citedByCount "50" @default.
• W2073639876 countsByYear W20736398762012 @default.
• W2073639876 countsByYear W20736398762013 @default.
• W2073639876 countsByYear W20736398762014 @default.
• W2073639876 countsByYear W20736398762015 @default.
• W2073639876 countsByYear W20736398762016 @default.
• W2073639876 countsByYear W20736398762017 @default.
• W2073639876 countsByYear W20736398762018 @default.
• W2073639876 countsByYear W20736398762019 @default.
• W2073639876 countsByYear W20736398762020 @default.
• W2073639876 countsByYear W20736398762021 @default.
• W2073639876 countsByYear W20736398762022 @default.
• W2073639876 countsByYear W20736398762023 @default.
• W2073639876 crossrefType "journal-article" @default.
• W2073639876 hasAuthorship W2073639876A5012376229 @default.
• W2073639876 hasAuthorship W2073639876A5017211359 @default.
• W2073639876 hasAuthorship W2073639876A5059226320 @default.
• W2073639876 hasAuthorship W2073639876A5072460133 @default.
• W2073639876 hasAuthorship W2073639876A5080101155 @default.
• W2073639876 hasConcept C113196181 @default.
• W2073639876 hasConcept C147789679 @default.
• W2073639876 hasConcept C150394285 @default.
• W2073639876 hasConcept C178790620 @default.
• W2073639876 hasConcept C179104552 @default.
• W2073639876 hasConcept C184651966 @default.
• W2073639876 hasConcept C185592680 @default.
• W2073639876 hasConcept C199289684 @default.
• W2073639876 hasConcept C2775832776 @default.
• W2073639876 hasConcept C2776062231 @default.
• W2073639876 hasConcept C2777787761 @default.
• W2073639876 hasConcept C2778891929 @default.

• next