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• W2073639921 abstract "μ3-Silyl complexes (Cp*Ru)2(Cp*M)(μ3-H2SiR)(μ-H)3 (4, M = Co; 5, M = Rh; 6, M = Ir) were synthesized by the reaction of trinuclear heterometallic clusters of Ru and group 9 metals, (Cp*Ru)2(Cp*M)(μ-H)3(μ3-H) (1, M = Co; 2, M = Rh; 3, M = Ir), with primary silanes. The unprecedented coordination mode of primary silanes on a trimetallic plane was unambiguously confirmed by means of multinuclear NMR spectroscopy, IR spectroscopy, and X-ray diffraction studies. The μ-silane complex (Cp*Ru)2(Cp*Ir)(μ-H2SiHtBu)(μ-H)4 (7), which is a plausible intermediate en route to the μ3-silyl complex, was obtained by the reaction of 3 with tBuSiH3. The μ3-silyl complex 6a was transformed into the μ-silyl complex (Cp*Ru)2(Cp*Ir)(μ-H2SiPh)(tBuNC)(μ-H)3 (8) upon treatment with tBuNC. Complex 6a also reacted with CO to afford the μ3-silylene complex (Cp*Ru)2(Cp*Ir)(μ3-HSiPh)(μ-CO)(μ-H)2 (10) via the formation of the μ-silyl complex (Cp*Ru)2(Cp*Ir)(μ-H2SiPh)(CO)(μ-H)3 (9)." @default.
• W2073639921 created "2016-06-24" @default.
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• W2073639921 date "2014-12-01" @default.
• W2073639921 modified "2023-09-23" @default.
• W2073639921 title "Trinuclear μ₃-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ₃-Silyl Complex of Ru₂Ir into μ-Silyl and μ₃-Silylene Complexes" @default.
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• W2073639921 doi "https://doi.org/10.1021/om5010308" @default.
• W2073639921 hasPublicationYear "2014" @default.
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