Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073640797> ?p ?o ?g. }
- W2073640797 endingPage "1576" @default.
- W2073640797 startingPage "1569" @default.
- W2073640797 abstract "The first steps of acetylene chain growth at AlEt3, via migratory insertion, have been investigated both experimentally and theoretically. The first insertion into the Al−Et bond occurs readily, leading to the stable alkenyl-bridged dimer [{Et2Al(μ-CH═CHEt)}2] (1). The alkenyl bridging mode has been observed through isolation and structural analysis of Al2Et2(OC6H3Ph2)2(μ-CH═CHEt)(μ-OC6H3Ph2) (2), synthesized by way of controlled reaction of 1 with 2,6-Ph2C6H3OH. This stable binding mode increases the barrier to a second insertion of acetylene, as insertion proceeds through monomeric Al-acetylene adducts. The energetics of further chain growth, dimer formation, and chain termination via hydrogenolysis were investigated theoretically. The results provide further insight and explanation for previous experimental findings in relation to the Aufbau reaction with acetylene." @default.
- W2073640797 created "2016-06-24" @default.
- W2073640797 creator A5002639740 @default.
- W2073640797 creator A5010517635 @default.
- W2073640797 creator A5013000968 @default.
- W2073640797 creator A5052630690 @default.
- W2073640797 creator A5072880741 @default.
- W2073640797 date "2011-02-23" @default.
- W2073640797 modified "2023-10-11" @default.
- W2073640797 title "Revisiting the Aufbau Reaction with Acetylene: Further Insights from Experiment and Theory" @default.
- W2073640797 cites W1965132755 @default.
- W2073640797 cites W1965278781 @default.
- W2073640797 cites W1971275758 @default.
- W2073640797 cites W1973326724 @default.
- W2073640797 cites W1975708211 @default.
- W2073640797 cites W1983759499 @default.
- W2073640797 cites W1998992115 @default.
- W2073640797 cites W2005678688 @default.
- W2073640797 cites W2015802353 @default.
- W2073640797 cites W2021884897 @default.
- W2073640797 cites W2023271753 @default.
- W2073640797 cites W2023549362 @default.
- W2073640797 cites W2025137678 @default.
- W2073640797 cites W2033990154 @default.
- W2073640797 cites W2037245884 @default.
- W2073640797 cites W2037506833 @default.
- W2073640797 cites W2044591029 @default.
- W2073640797 cites W2046412723 @default.
- W2073640797 cites W2047376727 @default.
- W2073640797 cites W2052111565 @default.
- W2073640797 cites W2052608904 @default.
- W2073640797 cites W2059854625 @default.
- W2073640797 cites W2061212347 @default.
- W2073640797 cites W2076623972 @default.
- W2073640797 cites W2079513964 @default.
- W2073640797 cites W2086957099 @default.
- W2073640797 cites W2096002684 @default.
- W2073640797 cites W2110035145 @default.
- W2073640797 cites W2139784076 @default.
- W2073640797 cites W2143981217 @default.
- W2073640797 cites W2148284063 @default.
- W2073640797 cites W2334799055 @default.
- W2073640797 cites W2520930298 @default.
- W2073640797 doi "https://doi.org/10.1021/om101114c" @default.
- W2073640797 hasPublicationYear "2011" @default.
- W2073640797 type Work @default.
- W2073640797 sameAs 2073640797 @default.
- W2073640797 citedByCount "9" @default.
- W2073640797 countsByYear W20736407972012 @default.
- W2073640797 countsByYear W20736407972013 @default.
- W2073640797 countsByYear W20736407972014 @default.
- W2073640797 countsByYear W20736407972017 @default.
- W2073640797 countsByYear W20736407972018 @default.
- W2073640797 crossrefType "journal-article" @default.
- W2073640797 hasAuthorship W2073640797A5002639740 @default.
- W2073640797 hasAuthorship W2073640797A5010517635 @default.
- W2073640797 hasAuthorship W2073640797A5013000968 @default.
- W2073640797 hasAuthorship W2073640797A5052630690 @default.
- W2073640797 hasAuthorship W2073640797A5072880741 @default.
- W2073640797 hasConcept C108204754 @default.
- W2073640797 hasConcept C137955730 @default.
- W2073640797 hasConcept C147597530 @default.
- W2073640797 hasConcept C152365726 @default.
- W2073640797 hasConcept C161790260 @default.
- W2073640797 hasConcept C174348530 @default.
- W2073640797 hasConcept C178790620 @default.
- W2073640797 hasConcept C181886296 @default.
- W2073640797 hasConcept C185592680 @default.
- W2073640797 hasConcept C188027245 @default.
- W2073640797 hasConcept C2777517455 @default.
- W2073640797 hasConcept C2779546866 @default.
- W2073640797 hasConcept C2779909098 @default.
- W2073640797 hasConcept C31258907 @default.
- W2073640797 hasConcept C41008148 @default.
- W2073640797 hasConcept C71240020 @default.
- W2073640797 hasConcept C75473681 @default.
- W2073640797 hasConceptScore W2073640797C108204754 @default.
- W2073640797 hasConceptScore W2073640797C137955730 @default.
- W2073640797 hasConceptScore W2073640797C147597530 @default.
- W2073640797 hasConceptScore W2073640797C152365726 @default.
- W2073640797 hasConceptScore W2073640797C161790260 @default.
- W2073640797 hasConceptScore W2073640797C174348530 @default.
- W2073640797 hasConceptScore W2073640797C178790620 @default.
- W2073640797 hasConceptScore W2073640797C181886296 @default.
- W2073640797 hasConceptScore W2073640797C185592680 @default.
- W2073640797 hasConceptScore W2073640797C188027245 @default.
- W2073640797 hasConceptScore W2073640797C2777517455 @default.
- W2073640797 hasConceptScore W2073640797C2779546866 @default.
- W2073640797 hasConceptScore W2073640797C2779909098 @default.
- W2073640797 hasConceptScore W2073640797C31258907 @default.
- W2073640797 hasConceptScore W2073640797C41008148 @default.
- W2073640797 hasConceptScore W2073640797C71240020 @default.
- W2073640797 hasConceptScore W2073640797C75473681 @default.
- W2073640797 hasIssue "6" @default.
- W2073640797 hasLocation W20736407971 @default.
- W2073640797 hasOpenAccess W2073640797 @default.
- W2073640797 hasPrimaryLocation W20736407971 @default.
- W2073640797 hasRelatedWork W1963513960 @default.