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- W2073648975 abstract "While a dimethyltantalum(V) complex of the [ONOcat]3− ligand ([ONOcat]H3 = N,N-bis(3,5-di-tert-butyl-2-phenol)amine) reacted with diazoalkane to afford products of insertion into the Ta−Me bond, the dichlorotantalum(V) complex [ONOcat]TaCl2(OEt2) reacted with 2 equiv of Ph2CN2 to form the ketazine adduct [ONOcat]TaCl2(η2(N,N′)-Ph2C═NN═CPh2). When Ph2CN2 was added to the dichloride in neat styrene, catalytic carbene transfer was observed to form the corresponding cyclopropane" @default.
- W2073648975 created "2016-06-24" @default.
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- W2073648975 date "2009-11-10" @default.
- W2073648975 modified "2023-10-16" @default.
- W2073648975 title "Reactivity of Diazoalkanes with Tantalum(V) Complexes of a Tridentate Amido-Bis(phenolate) Ligand" @default.
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- W2073648975 doi "https://doi.org/10.1021/om900701n" @default.
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