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- W2073665904 abstract "We investigate the liquid-vapor interface of a model of patchy colloids. This model consists of hard spheres decorated with short-ranged attractive sites (``patches'') of different types on their surfaces. We focus on a one-component fluid with two patches of type $A$ and nine patches of type $B$ $(2A9B$ colloids), which has been found to exhibit reentrant liquid-vapor coexistence curves and very low-density liquid phases. We have used the density-functional theory form of Wertheim's first-order perturbation theory of association, as implemented by Yu and Wu [J. Chem. Phys. 116, 7094 (2002)], to calculate the surface tension, and the density and degree of association profiles, at the liquid-vapor interface of our model. In reentrant systems, where $AB$ bonds dominate, an unusual thickening of the interface is observed at low temperatures. Furthermore, the surface tension versus temperature curve reaches a maximum, in agreement with Bernardino and Telo da Gama's mesoscopic Landau-Safran theory [Phys. Rev. Lett. 109, 116103 (2012)]. If $BB$ attractions are also present, competition between $AB$ and $BB$ bonds gradually restores the monotonic temperature dependence of the surface tension. Lastly, the interface is ``hairy,'' i.e., it contains a region where the average chain length is close to that in the bulk liquid, but where the density is that of the vapor. Sufficiently strong $BB$ attractions remove these features, and the system reverts to the behavior seen in atomic fluids." @default.
- W2073665904 created "2016-06-24" @default.
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- W2073665904 date "2015-01-05" @default.
- W2073665904 modified "2023-10-16" @default.
- W2073665904 title "Liquid-vapor interfaces of patchy colloids" @default.
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- W2073665904 doi "https://doi.org/10.1103/physreve.91.012301" @default.
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