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- W2073668638 abstract "Catalytic chain transfer is found to be useful for making telechelic oligomers with a variety of initiating groups in a one-step reaction procedure. Two olefinic components are required, the first being a normal free-radical-polymerizable monomer such as a methacrylate. The second is a vicinal or other olefin generally considered to be unreactive in free radical polymerizations. Under conditions of radical polymerization in the presence of a CCT catalyst, the copolymer that results incorporates predominantly one molecule of the second component at the initiation of each polymer chain. The terminal end group is a geminal double bond. This geminal-disubstituted end group is radically polymerizable and would allow the preparation of functionalized arms on graft polymers. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1911–1918, 2000" @default.
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- W2073668638 date "2000-05-15" @default.
- W2073668638 modified "2023-09-27" @default.
- W2073668638 title "Synthesis of telechelic polymers initiated with selected functional groups by catalytic chain transfer" @default.
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- W2073668638 doi "https://doi.org/10.1002/(sici)1099-0518(20000515)38:10<1911::aid-pola790>3.0.co;2-o" @default.
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