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- W2073669166 abstract "A flowing afterglow has been used to determine the rate coefficients and ion product distributions for the reactions of H+3 and H3O+ with the small organic molecules CH3OH,CH3CHO, C2H5OH, (CH3)2O, (CH3)2 CO and (C2H5)2O at 300 K. The rate coefficients for all the reactions are close to the average dipole orientation collisional values, indicating that the reactions have unit efficiency. However, the products for the H+3 and H3O+ reactions are very different. The H3O+ reactions proceed almost totally by non-dissociative proton transfer, as dictated by reaction energetics. The H+3 reactions are much more exothermic and non-dissociative proton transfer is not the only process, the reactions being dominated by many dissociative processes leading to the production of ions such as CH+3, HCO+, H3CO+, C2H+5 and C2H5O+. The data are compared with previous measurements where possible, and the mechanisms of the reactions are discussed." @default.
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- W2073669166 date "1992-09-01" @default.
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- W2073669166 title "Thermal energy reactions of H+3 and H3O+ with a series of small organic molecules" @default.
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- W2073669166 doi "https://doi.org/10.1016/0168-1176(92)80088-i" @default.
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