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• W2073679587 abstract "Abstract Five complexes of copper(II) acetate with Schiff base ligands based on salicylaldehyde and N,N-dimethylamino)ethyl/propyl amine and their reduced products, have been synthesized and characterized by various spectroscopic methods. The solid state structures of 1, 2 and 3 have been determined using single crystal X-ray diffraction method. The structures of the other two compounds have been proposed on the basis of spectroscopic and physical methods. The compounds 1, 3 and 4 are dinuclear complexes of the tridentate ligands, where the two Cu(II) centers have square pyramidal geometry with bridging acetate or phenoxo groups. Each arm of the tripodand ligand forms a mononuclear, magnetically dilute complex 5 having five coordinated Cu(II) ions. Complex 2 is mononuclear with a square pyramidal stereochemistry. The catalytic performance of the oxidation of 3,5-di-tert-butylcatechol to quinone was studied using UV–Vis absorption spectral methods. Complex 4 exhibits the highest activity with a turnover number of 41 h−1 while other showed lower rates of oxidation. A kinetic treatment on the basis of Michaelis–Menten model was applied. Ease of removal of the exogenous acetate ligands and easy access to the Cu(II) ions have been seen to affect the activity in the complexes. At the same time presence of two endogenous phenoxo bridges in the dinuclear complexes reduces the activity." @default.
• W2073679587 created "2016-06-24" @default.
• W2073679587 creator A5059897537 @default.
• W2073679587 creator A5064283701 @default.
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• W2073679587 creator A5087501209 @default.
• W2073679587 date "2010-01-01" @default.
• W2073679587 modified "2023-09-23" @default.
• W2073679587 title "Synthesis, crystal structure, spectral and magnetic studies and catecholase activity of copper(II) complexes with di- and tri-podal ligands" @default.
• W2073679587 cites W1911537859 @default.
• W2073679587 cites W1965509185 @default.
• W2073679587 cites W1966114000 @default.
• W2073679587 cites W1966306532 @default.
• W2073679587 cites W1966794157 @default.
• W2073679587 cites W1968817417 @default.
• W2073679587 cites W1969635440 @default.
• W2073679587 cites W1970155592 @default.
• W2073679587 cites W1972254901 @default.
• W2073679587 cites W1975817905 @default.
• W2073679587 cites W1977925490 @default.
• W2073679587 cites W1981373094 @default.
• W2073679587 cites W1981902642 @default.
• W2073679587 cites W1987946870 @default.
• W2073679587 cites W1991589087 @default.
• W2073679587 cites W1992380086 @default.
• W2073679587 cites W1993270072 @default.
• W2073679587 cites W1998722626 @default.
• W2073679587 cites W2000375726 @default.
• W2073679587 cites W2004239050 @default.
• W2073679587 cites W2005234903 @default.
• W2073679587 cites W2008584788 @default.
• W2073679587 cites W2013862228 @default.
• W2073679587 cites W2015553869 @default.
• W2073679587 cites W2016193130 @default.
• W2073679587 cites W2016289518 @default.
• W2073679587 cites W2018763502 @default.
• W2073679587 cites W2019347060 @default.
• W2073679587 cites W2023809317 @default.
• W2073679587 cites W2025130425 @default.
• W2073679587 cites W2025362358 @default.
• W2073679587 cites W2027333770 @default.
• W2073679587 cites W2028291957 @default.
• W2073679587 cites W2029232225 @default.
• W2073679587 cites W2029816958 @default.
• W2073679587 cites W2034772825 @default.
• W2073679587 cites W2038246362 @default.
• W2073679587 cites W2040577559 @default.
• W2073679587 cites W2042115572 @default.
• W2073679587 cites W2047940948 @default.
• W2073679587 cites W2049597257 @default.
• W2073679587 cites W2050076483 @default.
• W2073679587 cites W2050645337 @default.
• W2073679587 cites W2051933804 @default.
• W2073679587 cites W2053535968 @default.
• W2073679587 cites W2057493249 @default.
• W2073679587 cites W2059401704 @default.
• W2073679587 cites W2059553922 @default.
• W2073679587 cites W2059652206 @default.
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• W2073679587 cites W2063334178 @default.
• W2073679587 cites W2063372175 @default.
• W2073679587 cites W2065275256 @default.
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• W2073679587 cites W2075367249 @default.
• W2073679587 cites W2077834700 @default.
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• W2073679587 cites W2084527803 @default.
• W2073679587 cites W2084847950 @default.
• W2073679587 cites W2088261533 @default.
• W2073679587 cites W2093102953 @default.
• W2073679587 cites W2102455520 @default.
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• W2073679587 cites W2113954851 @default.
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• W2073679587 cites W2324212025 @default.
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• W2073679587 doi "https://doi.org/10.1016/j.ica.2009.09.041" @default.
• W2073679587 hasPublicationYear "2010" @default.
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