Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073698539> ?p ?o ?g. }
- W2073698539 endingPage "2700" @default.
- W2073698539 startingPage "2693" @default.
- W2073698539 abstract "The first synthesis and characterization of sigma-bonded and N-substituted cobalt porphycenes is reported. The investigated compounds are represented as (Pc)Co(R) and (N-CH(3)OEPc)CoCl, where R is CH(3) or C(6)H(5), Pc is the dianion of 2,3,6,7,12,13,16,17-octaethylporphycene (OEPc), 2,7,12,17-tetrapropylporphycene (TPrPc), or 2,7,12,17-tetraethyl-3,6,13,16-tetramethylporphycene (EtioPc), N-CH(3)OEPc is the monoanion of N-methyl-2,3,6,7,12,13,16,17-octaethylporphycene. Each sigma-bonded (Pc)Co(R) derivative can be reversibly reduced or oxidized by two electrons, but a slow migration of the sigma-bonded R group occurs following electrogeneration of [(Pc)Co(R)](+)()(*)() leading, as a final product, to an N-substituted cobalt(II) porphycene which is also electroactive and undergoes two reductions in PhCN. The singly reduced product of this reaction is formulated as a Co(II) pi-anion radical which undergoes a slow back-migration of the CH(3) group to regenerate (OEPc)Co(CH(3))." @default.
- W2073698539 created "2016-06-24" @default.
- W2073698539 creator A5051818947 @default.
- W2073698539 creator A5059917671 @default.
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- W2073698539 creator A5082814364 @default.
- W2073698539 creator A5083189522 @default.
- W2073698539 creator A5085421800 @default.
- W2073698539 creator A5091399343 @default.
- W2073698539 date "1998-05-09" @default.
- W2073698539 modified "2023-10-18" @default.
- W2073698539 title "Synthesis and Electrochemical Reactivity of σ-Bonded and N-Substituted Cobalt Porphycenes" @default.
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