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• W2073706989 abstract "2-Methylresorcinarene and its methylene-bridged cavitand derivative as host compounds were investigated in selective complexation of alkali metal ions as guests in methanol media by photoluminescence measurements. These host molecules possess either flexible (2-methylresorcinarene) or rigid (cavitand) molecular skeleton. The Benesi–Hildebrand method and the van't Hoff theory have been applied to determine the stability constants and the thermodynamic parameters, respectively. Considerable interactions between 2-methylresorcinarene and Li+ or Na+ ions have been observed while the rigid cavitand derivative can interact only with K+ or Cs+ ions. Neither the complexes of 2-methylresorcinarene with K+ or Cs+ nor those of the cavitand derivative with Li+ or Na+ ions are stable at room temperature in methanol media. Quantum-chemical investigations justified that only solvated Li+ and Na+ ions can form stable complexes with 2-methylresorcinarene while unsolvated K+ and Cs+ ions form stable complexes with the methylene-bridged cavitand. These results highlight that the stability of the guest solvation shell and its size could play a key role in the selectivity behaviour of host molecules." @default.
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• W2073706989 date "2012-06-01" @default.
• W2073706989 modified "2023-10-03" @default.
• W2073706989 title "The role of the solvation shell decomposition of alkali metal ions in their selective complexation by resorcinarene and its cavitand" @default.
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• W2073706989 doi "https://doi.org/10.1080/10610278.2012.678358" @default.
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