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- W2073711345 abstract "The crystal structure of dimeric {Ti 2 [μ- m -C 6 H 4 (COOET) 2 ] 2 Cl 8 }, which in the presence of activators is a good catalyst for olefin polymerization, has been determined by X-ray diffraction and refined by full-matrix least squares to R = 0.0333 for 1990 independent non-zero reflexions. Crystals are triclinic, space group P 1 , Z = 1, in a cell of dimensions: a = 8.940(5), b = 10.466(8), c = 10.427(8) Å, α = 97.28(6), β = 107.61(4), γ = 108.13(4)°. The crystal consists of dimeric molecules possessing crystallographic symmetry centre. The titanium atoms are octahedrally coordinated by four chlorine atoms and two carbonyl oxygen atoms of the two m -diethylphthalate in the cis position. The two ester ligands and the two Ti atoms form a sixteen-membered ring. The phenyl rings are not quite planar; the average separation between them is 3.36(1) Å." @default.
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- W2073711345 date "1989-09-01" @default.
- W2073711345 modified "2023-10-16" @default.
- W2073711345 title "The crystal structure and properties of di-μ-m-diethylphthalateoctachlorodititanium(IV)" @default.
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- W2073711345 doi "https://doi.org/10.1016/0022-328x(89)85025-9" @default.
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