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• W2073736741 abstract "Abstract We report the results of a quasiclassical trajectory investigation of the reaction probability ( P R ) as a function of relative translational energy for the title reaction, with H 2 in its ground vibrational state ( v =0) in collinear geometry on the Starck-Meyer ab initio potential energy surface and compare them with quantum mechanical results. Results for H − ,D 2 collisions under identical conditions are compared with experimental results. The nature of the dynamics is investigated by examining the dependence of final vibrational action on the initial vibrational phase ( φ i ) and by examining Poincare surface of section plots for individual trajectories in hyperbolic coordinates. It is found that the dynamics is regular when P R is either zero or unity. But when 0 P R" @default.
• W2073736741 created "2016-06-24" @default.
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• W2073736741 date "1998-06-01" @default.
• W2073736741 modified "2023-09-27" @default.
• W2073736741 title "Classical mechanical investigation of collinear H− + H2 → H2 + H− dynamics" @default.
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• W2073736741 doi "https://doi.org/10.1016/s0009-2614(98)00450-3" @default.
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