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- W2073747825 abstract "Reaction of dibutyltin oxides, xBu2SnO [x = n (normal), i (iso), s (secondary) and t (tertiary)] with carboxylic acids [RCOOH; R CH3, (Me), CH3CH2 (Et), (CH3)2CH (iPr) and (CH3)3C (tBu)] in 1:1 and 1:2 stoichiometry were investigated. The products formed in these reactions were characterized by elemental analyses, IR and NMR (1H, 13C and 119Sn) data. Reactions in 1:2 stoichiometry afforded dibutyltin dicarboxylates which have six-coordinate tin atom. Steric effects of the butyl group and the R group of the carboxylate ligand play an important role in 1:1 reactions. Dicarboxylatotetraorganostannoxanes were formed with nBu2SnO while hydroxo complexes, [tBu2Sn(μ-OH)(OOCR)]2 were the sole products with tBu2SnO. The stereochemistry of all these complexes is discussed on the basis of NMR data." @default.
- W2073747825 created "2016-06-24" @default.
- W2073747825 creator A5038152688 @default.
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- W2073747825 date "1992-12-01" @default.
- W2073747825 modified "2023-10-18" @default.
- W2073747825 title "Steric effects on the formation of isolable products in the reactions of dibutyltin oxides with carboxylic acids" @default.
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- W2073747825 doi "https://doi.org/10.1016/0022-328x(92)83381-q" @default.
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