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- W2073749587 abstract "Rhodium-catalyzed [4 + 3] cycloaddition between methyl 2-(siloxy)vinyldiazoacetate and pyrroles results in the enantioselective synthesis of highly functionalized 8-azabicyclo[3.2.1]octa-2,6-dienes (tropanes). The reaction proceeds via a rhodium−carbenoid intermediate and involves a tandem cyclopropanation/Cope rearrangement mechanism. The optimum chiral dirhodium catalyst for this transformation is the adamantyl glycine-derived complex, Rh2(S-PTAD)4." @default.
- W2073749587 created "2016-06-24" @default.
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- W2073749587 date "2007-08-01" @default.
- W2073749587 modified "2023-10-07" @default.
- W2073749587 title "Asymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] Cycloaddition" @default.
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- W2073749587 doi "https://doi.org/10.1021/ja072936e" @default.
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