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- W2073751517 abstract "Abstract A series of new ring-expanded isosteres (1,4-oxaheteroepanes) of Ftorafur [1-(2-tetrahydrofuranyl)-5-fluorouracil] has been synthesized. The branching of C-3 of the seven-membered cycloacetal and the electronegativity of the Y group on the 3-YCH2 moities (Y being H, I and Cl), respectively, seem to direct their regiochemical and stereochemical outcome. The more electronegative the group Y is (and favouring accordingly the formation of an external ion pair), the more diastereoselectivity that is reached. The in vitro cytotoxicity versus HT-29 has been tested, showing that cis-3g was the only moderately active compound." @default.
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- W2073751517 date "1998-10-01" @default.
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- W2073751517 title "Synthesis of novel 5-fluorouracil derivatives with 1,4-oxaheteroepane moieties" @default.
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- W2073751517 doi "https://doi.org/10.1016/s0040-4020(98)00815-1" @default.
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