FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073755429> ?p ?o ?g. }

• W2073755429 endingPage "14077" @default.
• W2073755429 startingPage "14074" @default.
• W2073755429 abstract "An aromatic saddle was designed from the hypothetical three-dimensional graphene with the negative Gaussian curvature (Schwarzite P192). Two aromatic saddles, tetrabenzo[8]circulene (TB8C) and its octamethyl derivative OM-TB8C, were synthesized by the Scholl reaction of cyclic octaphenylene precursors. The structure of TB8C greatly deviates from planarity, and the deep saddle shape was confirmed by single-crystal X-ray crystallography. There are two conformers with the S4 symmetry, which are twisted compared to the DFT structure (D2d). The theoretical studies propose that the interconversion of TB8C via the planar transition state (125 kcal mol(-1)) is not possible. However, the pseudorotation leads to a low-energy tub-to-tub inversion via the nonplanar transition state (7.3 kcal mol(-1)). The ground-state structure of TB8C in solution is quite different from the X-ray structure because of the crystal-packing force and low-energy pseudorotation. OM-TB8C is a good electron donor and works as the p-type semiconductor." @default.
• W2073755429 created "2016-06-24" @default.
• W2073755429 creator A5016383134 @default.
• W2073755429 creator A5065378321 @default.
• W2073755429 date "2013-09-12" @default.
• W2073755429 modified "2023-10-18" @default.
• W2073755429 title "Tetrabenzo[8]circulene: Aromatic Saddles from Negatively Curved Graphene" @default.
• W2073755429 cites W1965741769 @default.
• W2073755429 cites W1969572849 @default.
• W2073755429 cites W1975110717 @default.
• W2073755429 cites W1979966879 @default.
• W2073755429 cites W1982793684 @default.
• W2073755429 cites W1983266264 @default.
• W2073755429 cites W1991714308 @default.
• W2073755429 cites W2000552853 @default.
• W2073755429 cites W2007311384 @default.
• W2073755429 cites W2014173382 @default.
• W2073755429 cites W2018858346 @default.
• W2073755429 cites W2027537320 @default.
• W2073755429 cites W2031158625 @default.
• W2073755429 cites W2042806090 @default.
• W2073755429 cites W2048542010 @default.
• W2073755429 cites W2051146701 @default.
• W2073755429 cites W2053248916 @default.
• W2073755429 cites W2059487431 @default.
• W2073755429 cites W2070138360 @default.
• W2073755429 cites W2082449151 @default.
• W2073755429 cites W2090035581 @default.
• W2073755429 cites W2095431859 @default.
• W2073755429 cites W2105414764 @default.
• W2073755429 cites W2118620488 @default.
• W2073755429 cites W2142528004 @default.
• W2073755429 cites W2144787285 @default.
• W2073755429 cites W2156739932 @default.
• W2073755429 cites W2166179929 @default.
• W2073755429 cites W2167181584 @default.
• W2073755429 cites W2167579892 @default.
• W2073755429 cites W2326103891 @default.
• W2073755429 cites W2498887189 @default.
• W2073755429 cites W2949116157 @default.
• W2073755429 cites W2950086506 @default.
• W2073755429 cites W4247973484 @default.
• W2073755429 doi "https://doi.org/10.1021/ja407842z" @default.
• W2073755429 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24015972" @default.
• W2073755429 hasPublicationYear "2013" @default.
• W2073755429 type Work @default.
• W2073755429 sameAs 2073755429 @default.
• W2073755429 citedByCount "192" @default.
• W2073755429 countsByYear W20737554292014 @default.
• W2073755429 countsByYear W20737554292015 @default.
• W2073755429 countsByYear W20737554292016 @default.
• W2073755429 countsByYear W20737554292017 @default.
• W2073755429 countsByYear W20737554292018 @default.
• W2073755429 countsByYear W20737554292019 @default.
• W2073755429 countsByYear W20737554292020 @default.
• W2073755429 countsByYear W20737554292021 @default.
• W2073755429 countsByYear W20737554292022 @default.
• W2073755429 countsByYear W20737554292023 @default.
• W2073755429 crossrefType "journal-article" @default.
• W2073755429 hasAuthorship W2073755429A5016383134 @default.
• W2073755429 hasAuthorship W2073755429A5065378321 @default.
• W2073755429 hasConcept C115624301 @default.
• W2073755429 hasConcept C147597530 @default.
• W2073755429 hasConcept C171250308 @default.
• W2073755429 hasConcept C178790620 @default.
• W2073755429 hasConcept C185592680 @default.
• W2073755429 hasConcept C18705241 @default.
• W2073755429 hasConcept C192562407 @default.
• W2073755429 hasConcept C195065555 @default.
• W2073755429 hasConcept C2524010 @default.
• W2073755429 hasConcept C2779413573 @default.
• W2073755429 hasConcept C30080830 @default.
• W2073755429 hasConcept C32909587 @default.
• W2073755429 hasConcept C33923547 @default.
• W2073755429 hasConcept C68260962 @default.
• W2073755429 hasConcept C71240020 @default.
• W2073755429 hasConcept C8010536 @default.
• W2073755429 hasConceptScore W2073755429C115624301 @default.
• W2073755429 hasConceptScore W2073755429C147597530 @default.
• W2073755429 hasConceptScore W2073755429C171250308 @default.
• W2073755429 hasConceptScore W2073755429C178790620 @default.
• W2073755429 hasConceptScore W2073755429C185592680 @default.
• W2073755429 hasConceptScore W2073755429C18705241 @default.
• W2073755429 hasConceptScore W2073755429C192562407 @default.
• W2073755429 hasConceptScore W2073755429C195065555 @default.
• W2073755429 hasConceptScore W2073755429C2524010 @default.
• W2073755429 hasConceptScore W2073755429C2779413573 @default.
• W2073755429 hasConceptScore W2073755429C30080830 @default.
• W2073755429 hasConceptScore W2073755429C32909587 @default.
• W2073755429 hasConceptScore W2073755429C33923547 @default.
• W2073755429 hasConceptScore W2073755429C68260962 @default.
• W2073755429 hasConceptScore W2073755429C71240020 @default.
• W2073755429 hasConceptScore W2073755429C8010536 @default.
• W2073755429 hasIssue "38" @default.
• W2073755429 hasLocation W20737554291 @default.
• W2073755429 hasLocation W20737554292 @default.
• W2073755429 hasOpenAccess W2073755429 @default.
• W2073755429 hasPrimaryLocation W20737554291 @default.

• next