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• W2073769811 abstract "A peak appearing at the L2,3 X-ray absorption edge often provides the number of empty d states of the X-ray absorbing atoms. Ag+ compounds have a d10 state (no d empty states) but show a small peak at the edge. In this research, we systematically studied the edge peak of Ag+ compounds to understand its origin on the basis of the molecular orbital picture and to obtain a relation of the edge peak intensity to chemical and physical quantities. The edge peak can be formally assigned to the transition from 2p to 5s enhanced by the s−d hybridization. The peak intensity has a negative correlation with a coordination charge but has a positive correlation with the strength of the covalent bond, which is in the reverse order to the other dn (n < 10) elements." @default.
• W2073769811 created "2016-06-24" @default.
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• W2073769811 date "2010-03-08" @default.
• W2073769811 modified "2023-10-02" @default.
• W2073769811 title "Ag L₃-Edge X-ray Absorption Near-Edge Structure of 4d¹⁰ (Ag⁺) Compounds: Origin of the Edge Peak and Its Chemical Relevance" @default.
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• W2073769811 doi "https://doi.org/10.1021/jp907669s" @default.
• W2073769811 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20210323" @default.
• W2073769811 hasPublicationYear "2010" @default.
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