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- W2073790367 abstract "Durch langwelliges UV-Licht (>300 nm) werden die Enamide 3 zum S1-Zustand angeregt, der nach Übergang in den T1-Zustand eine cis-trans-Isomerisierung auslöst, die sich auch photosensibilisiert erreichen läßt. Bei Bestrahlung mit ungefiltertem UV-Licht werden die Enamide 3 zusätzlich zum S2-Zustand angeregt, der sich unter 1.3-Acylverschiebung zu 5 stabilisiert. Diese 1.3-Acylverschiebung verläuft teilweise intermolekular, wobei die Acylgruppe als Radikal wandert." @default.
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- W2073790367 date "1969-09-01" @default.
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- W2073790367 title "Photochemie aus höher angeregten Zuständen: Photoumlagerungen in Enamiden" @default.
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- W2073790367 doi "https://doi.org/10.1002/cber.19691020914" @default.
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