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- W2073847304 abstract "The complexes [MoH(SC6H2R3-2,4,6)3(PR′Ph2)]1(R = Me or Pri, R′= Me or Et) have been prepared by reaction of HSC6H2R3-2,4,6 with [MoH4(PR′Ph2)4] or trans-[Mo(N2)2(PR′Ph2)4]. Compound 1(R = Pri, R′= Me) reacted with N-donor ligands L (C5H5N, 3-MeC5H4N, 3,5-Me2C5H3N or C3H3NS) to give the adducts 2, [MoH(SC6H2Pri3-2,4,6)3L(PMePh2)]. The crystal structure of the analogue [MoH(SC6H2Pri3-2,4,6)3(C5H5N)(PMe2Ph)] showed the compound to have a trigonal girdle of thiolate ligands with the pyridine and PMe2Ph ligands in essentially apical positions. Reaction of 1(R = Pri, R′= Et) with NC5H4SH-2 gave the seven-co-ordinate complex [MoH(SC6H2Pri3-2,4,6)(NC5H4S-2)2-(PEtPh2)], shown by X-ray crystallography to have an essentially pentagonal-pyramidal geometry with the hydride located in the equatorial plane. Spectroscopic data for the compounds are discussed in terms of their structures. Complex 1(R = Pri, R′= Et) exchanges hydride for deuteride on treatment with deuterium gas in benzene at 20 °C. Treatment of 1(R = Pri, R′= Me) in MeOH with LiBEt3H, followed by [PPh4]Cl, gave [PPh4][MoO(SC6H2Pri3-2,4,6)4], shown by X-ray crystallography to have an anion with square-pyramidal geometry and an apical oxide-ligand." @default.
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- W2073847304 date "1995-01-01" @default.
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- W2073847304 title "Five-co-ordinate complexes [MoH(SC<sub>6</sub>H<sub>2</sub>R<sub>3</sub>-2,4,6)<sub>3</sub>(PR′Ph<sub>2</sub>)](R = Me or Pr<sup>i</sup>, R′= Me or Et) and their reactions with nitrogen donors. Crystal structures of [MoH(SC<sub>6</sub>H<sub>2</sub>Pr<sup>i</sup><sub>3</sub>-2,4,6)<sub>3</sub>(C<sub>5</sub>H<sub>5</sub>N)(PMe<sub>2</sub>Ph)], [MoH(NC<sub>5</sub>H<sub>4</sub>S-2)<sub>2</sub>(SC<sub>6</sub>H<sub>2</sub>Pr<sup>i</sup><sub>3</sub>-2,4,6)(PEtPh<sub>2</sub>)] and [PPh<sub>4</sub>][MoO…" @default.
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- W2073847304 doi "https://doi.org/10.1039/dt9950000005" @default.
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