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• W2073853529 abstract "The two parameter hard-sphere equation of state used by Snider and Herrington to calculate excess functions for mixtures of condensed gases near their boiling points has been modified to take account of the fact that over a range of temperature the parameters are not constant. The parameter which represents the size of the molecules has been treated as a function of volume, while that associated with the intermolecular energy of attraction has been treated as a function of temperature. Excess functions calculated using the modified equation in general show improved agreement with the experimental values. Moreover the new equation has been used to predict the excess functions of binary mixtures of condensed gases over wide ranges of temperature and pressure, both for systems which have already been partially studied experimentally and for others (for example, fluorine + argon) for which no data yet exist." @default.
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• W2073853529 date "1973-02-01" @default.
• W2073853529 modified "2023-09-27" @default.
• W2073853529 title "The prediction of the excess functions of liquid mixtures using a modified hard-sphere equation of state" @default.
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• W2073853529 doi "https://doi.org/10.1016/0011-2275(73)90131-8" @default.
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