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- W2073867929 abstract "The tetradentate ligand 2,3,4,5-tetra(pyrid-2-yl)cyclopent-2,4-dien-1-one (3) was prepared and used for the synthesis of the dinuclear chelates [μ-(3)(MX2)2] (MX2 = BeCl2, ZnCl2, ZnBr2, HgCl2, HgBr2); the closely related BeCl2 chelate of the bidentate ligand 2,5-diphenyl-3,4-di(pyrid-2-yl)cyclopent-2,4-dien-1-one (1) was also prepared. The structures of these compounds were determined by X-ray crystallography and compared to those of the corresponding unchelated analogues [(py)2MX2] (py = pyridine). Aggregation to polymeric chains by chloro-bridging was observed for [μ-(3)(HgCl2)2] in the crystal." @default.
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- W2073867929 date "2008-05-01" @default.
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- W2073867929 title "Chelate Complexes of the Pyrid-2-yl Analogue of Tetracyclone" @default.
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- W2073867929 doi "https://doi.org/10.1002/zaac.200700550" @default.
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