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- W2073875504 abstract "Reaction of the electron-rich olefin [Et[graphic omitted]]2 with tellurium affords the thermally or photochemically labile Et[graphic omitted]Te which reacts with [M(CO)5(NCMe)](M = Cr, Mo, or W) or [NEt4][MnBr2(CO)4] to yield [M(CO)5{Te[graphic omitted]Et}] or cis-[Mn(Br)(CO)4{Te[graphic omitted]Et}]; the compound [Cr(CO)5{Te[graphic omitted]Et}] is readily detellurated to yield the carbenemetal complex [Cr(CO)5{[graphic omitted]Et}]; the molecule of the title compound lies on a crystallographic mirror plane with the carbene ligand perpendicular to this plane and Te–Cr = 2·765(4), Te–Ccarb= 2·12(2)Å, and ∠ Cr–Te–Ccarb= 96·1(5)°." @default.
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- W2073875504 date "1980-01-01" @default.
- W2073875504 modified "2023-10-11" @default.
- W2073875504 title "Telluroureas and derived transition metal complexes: the crystal and molecular structure of [Cr(CO)<sub>5</sub>{TeCN(Et)CH<sub>2</sub>CH<sub>2</sub>NEt}]" @default.
- W2073875504 doi "https://doi.org/10.1039/c39800000635" @default.
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