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- W2073884998 abstract "1,1 unimolecular hydrogen eliminations from carbocations are currently interpreted in terms of a concerted mechanism in which two CH bonds are synchronously stretched. Here we show, through MNDO and RRKM computations, that the available experimental data are compatible with all the reaction mechanisms in which both the CH bonds are significantly distorted in the transition state, irrespective of the synchronous or non-synchronous character of the reaction." @default.
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- W2073884998 date "1983-07-01" @default.
- W2073884998 modified "2023-09-23" @default.
- W2073884998 title "Transition state structure and isotope effects in unimolecular hydrogen elimination from carbocations" @default.
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- W2073884998 doi "https://doi.org/10.1016/0009-2614(83)80088-8" @default.
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