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- W2073896107 abstract "Abstract Nitration of9-tosylcarbazole in acetic anhydride solution gives l-nitro (28%), 2-nitro (19%) and 3-nitro (53%) derivatives. The mixture of the nitro compounds obtained from 9-acetylcarbazole contains 10%, 48% and 42% of the isomers, respectively. Under similar conditions 9-nitrosocarbazole shows a different isomer distribution: 34% of 1-nitro and 66% of 3-nitrocarbazole. Nitration of carbazole is a two step process involving formation and rearrangement of 9-nitrocarbazole. The hypothesis was supported by the results of 1,3,6,8-tetrachlorocarbazole nitration and oxidation of 9-nitrosocarbazole and rearrangement of 9-nitrocarbazole in the nitration conditions." @default.
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- W2073896107 date "1984-01-01" @default.
- W2073896107 modified "2023-09-25" @default.
- W2073896107 title "Nitration in the carbazole series" @default.
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- W2073896107 doi "https://doi.org/10.1016/s0040-4020(01)91140-8" @default.
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