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- W2073911478 abstract "Micronic ZSM5 (Si/Al = 25) powder has been deposited on cordierite monoliths by dip-coating technique using colloidal alumina or silica as binders with different zeolite/binder ratios in aqueous suspension determining the parameters to obtain the best adhesion and mechanical resistance of the washcoat layer. For monolithic catalysts with washcoat containing 10 wt% SiO2 the following alternative preparation procedures have been used: (i) deposition of a pre-exchanged Cu-ZSM5 powder on the ceramic monolith; (ii) deposition of a H-ZSM5 powder on the ceramic monolith followed by copper exchange of the structured catalyst. The monolithic catalysts have been investigated by morphological (SEM), physical (BET and porosity), chemical (ICP-MS, EDX, XRD, H2 TPR) and catalytic (NO decomposition tests in flow reactor under dry and wet conditions) analyses. Results have been compared with those obtained on the corresponding Cu-ZSM5 powder sample with the same copper content and Si/Al ratio in order to define the effect of the preparation procedure on the chemical and catalytic properties of the monoliths." @default.
- W2073911478 created "2016-06-24" @default.
- W2073911478 creator A5023028805 @default.
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- W2073911478 creator A5036662015 @default.
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- W2073911478 date "2009-11-01" @default.
- W2073911478 modified "2023-09-24" @default.
- W2073911478 title "Cu-ZSM5 based monolith reactors for NO decomposition" @default.
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- W2073911478 doi "https://doi.org/10.1016/j.cej.2009.04.025" @default.
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