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- W2073920194 abstract "These rearrangements are both of first-order in hydrazo-compound and of first-order in hydrogen ions over the measured 500- or 700-fold range of hydrogen-ion concentration. The sole rearrangement product from 2,2′-dimethoxyhydrazobenzene is 3,3′-dimethoxybenzidine: a small amount of disproportionation accompanies rearrangement. Kinetically, this disproportionation has the same acid-dependence as the accompanying rearrangement. The main rearrangement product from 4-methoxyhydrazobenzene is an o-semidine; but it is accompanied by a substantial amount of the p-semidine, and by a substantial quantity of the products of disproportionation. The data show that this disproportionation has a kinetic form identical with that of the accompanying rearrangements." @default.
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- W2073920194 date "1968-01-01" @default.
- W2073920194 modified "2023-10-18" @default.
- W2073920194 title "Mechanism of benzidine and semidine rearrangements. Part XVII. Kinetics and products of the acid rearrangements of 2,2′-dimethoxy- and 4-methoxy-hydrazobenzene" @default.
- W2073920194 doi "https://doi.org/10.1039/j29680000605" @default.
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