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• W2073956875 abstract "The complete study of the vapour-liquid equilibrium of ternary systems with limited miscibility requires vapour-liquid equilibrium determinations and liquid-liquid equilibrium determinations at boiling point. The vapour-liquid equilibrium was determined by means of an equilibrium still based on the principle of Giilespie but modified in such a way that an accurate boiling point measurement, even for systems with heterogeneous liquid was possible and that the vapour phase was analysed without previous condensation. Two ternary systems have been studied: the system methanol-ethylacetate-water and the system ethanol-ethylacetate-water. The ternary data have been predicted by means of the equation of Renon and Prausnitz. The parameters are determined by correlating the binary data. The ternary vapour-liquid equilibrium are predicted within 1-2. 10 −2 mol fraction for the vapour composition and 1°C for the boiling point. The position of the predicted tielines of the liquid-liquid equilibrium at boiling point was almost coinciding with the position of the experimental tielines. There was a slight deviation of the predicted and experimental binodal." @default.
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• W2073956875 date "2007-04-25" @default.
• W2073956875 modified "2023-10-14" @default.
• W2073956875 title "The vapour-liquid equilibrium of ternary systems with limited miscibility at atmospheric pressure" @default.
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• W2073956875 doi "https://doi.org/10.1002/jctb.5020241202" @default.
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