Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073957993> ?p ?o ?g. }
- W2073957993 endingPage "330" @default.
- W2073957993 startingPage "322" @default.
- W2073957993 abstract "Semifluorinated self-assembled (FAS SA) films fabricated from trifunctional precursors are frequently used in myriad applications, yet an understanding of the effects of fabrication conditions, including deposition time, on adsorption mechanisms and molecular architectures is still being developed. In this work we prepared SA films based on the F(CF(2))(8)(CH(2))(2)SiCl(3) (FAS-17) precursor and characterized these films using a suite of surface analytical techniques. Contact angle, sum frequency generation (SFG) spectroscopy, X-ray photoelectron spectroscopy (XPS), and ellipsometry results are consistent with the formation of disordered sub-monolayer structures at short deposition times, well-ordered monolayers at intermediate deposition times, and inhomogeneous multilayers at long deposition times. Correlation of SFG and XPS results demonstrates a change in FAS-17 chain orientation as the deposition time increases from 2 s to 5 min. Group theory-based calculations, SFG studies, and Fourier-transform infrared (FTIR) results also afford additional evidence in support of the assignment of the SFG signals at ~1345 and ~1370 cm(-1) to the asymmetric stretching mode of the semifluorinated silane chain's terminal CF(3) group rather than to its axial CF(2) stretches. To our knowledge, this is the first report of SFG studies on semifluoroalkyl silane self-assembled films in the C-F stretching frequency region." @default.
- W2073957993 created "2016-06-24" @default.
- W2073957993 creator A5004391315 @default.
- W2073957993 creator A5016329638 @default.
- W2073957993 creator A5047855284 @default.
- W2073957993 creator A5051495533 @default.
- W2073957993 creator A5054123780 @default.
- W2073957993 creator A5070354722 @default.
- W2073957993 date "2011-01-01" @default.
- W2073957993 modified "2023-10-09" @default.
- W2073957993 title "Investigation of sub-monolayer, monolayer, and multilayer self-assembled semifluorinated alkylsilane films" @default.
- W2073957993 cites W1964188898 @default.
- W2073957993 cites W1965307135 @default.
- W2073957993 cites W1968073244 @default.
- W2073957993 cites W1973118111 @default.
- W2073957993 cites W1973702883 @default.
- W2073957993 cites W1975216008 @default.
- W2073957993 cites W1978679765 @default.
- W2073957993 cites W1979723206 @default.
- W2073957993 cites W1980149506 @default.
- W2073957993 cites W1980656139 @default.
- W2073957993 cites W1986001588 @default.
- W2073957993 cites W1986617369 @default.
- W2073957993 cites W1987176498 @default.
- W2073957993 cites W1987275010 @default.
- W2073957993 cites W1990607303 @default.
- W2073957993 cites W1991821478 @default.
- W2073957993 cites W1994553437 @default.
- W2073957993 cites W1995945701 @default.
- W2073957993 cites W2000131638 @default.
- W2073957993 cites W2002650530 @default.
- W2073957993 cites W2022166684 @default.
- W2073957993 cites W2026912561 @default.
- W2073957993 cites W2027375070 @default.
- W2073957993 cites W2028365184 @default.
- W2073957993 cites W2031799468 @default.
- W2073957993 cites W2032128691 @default.
- W2073957993 cites W2032286833 @default.
- W2073957993 cites W2034337706 @default.
- W2073957993 cites W2035304010 @default.
- W2073957993 cites W2037019009 @default.
- W2073957993 cites W2037855380 @default.
- W2073957993 cites W2037904817 @default.
- W2073957993 cites W2039534196 @default.
- W2073957993 cites W2045111209 @default.
- W2073957993 cites W2047226706 @default.
- W2073957993 cites W2047673827 @default.
- W2073957993 cites W2049334420 @default.
- W2073957993 cites W2053940175 @default.
- W2073957993 cites W2054836251 @default.
- W2073957993 cites W2057481220 @default.
- W2073957993 cites W2060606812 @default.
- W2073957993 cites W2067821192 @default.
- W2073957993 cites W2069200264 @default.
- W2073957993 cites W2070601866 @default.
- W2073957993 cites W2080411202 @default.
- W2073957993 cites W2083737403 @default.
- W2073957993 cites W2085873858 @default.
- W2073957993 cites W2086365876 @default.
- W2073957993 cites W2093502834 @default.
- W2073957993 cites W2096626321 @default.
- W2073957993 cites W2098908528 @default.
- W2073957993 cites W2102498367 @default.
- W2073957993 cites W2117669255 @default.
- W2073957993 cites W2118444379 @default.
- W2073957993 cites W2121242766 @default.
- W2073957993 cites W2129151312 @default.
- W2073957993 cites W2137419733 @default.
- W2073957993 cites W2165372810 @default.
- W2073957993 cites W2464552632 @default.
- W2073957993 cites W3099191823 @default.
- W2073957993 doi "https://doi.org/10.1016/j.jcis.2010.09.057" @default.
- W2073957993 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20947093" @default.
- W2073957993 hasPublicationYear "2011" @default.
- W2073957993 type Work @default.
- W2073957993 sameAs 2073957993 @default.
- W2073957993 citedByCount "26" @default.
- W2073957993 countsByYear W20739579932012 @default.
- W2073957993 countsByYear W20739579932013 @default.
- W2073957993 countsByYear W20739579932014 @default.
- W2073957993 countsByYear W20739579932015 @default.
- W2073957993 countsByYear W20739579932016 @default.
- W2073957993 countsByYear W20739579932018 @default.
- W2073957993 countsByYear W20739579932019 @default.
- W2073957993 countsByYear W20739579932021 @default.
- W2073957993 countsByYear W20739579932022 @default.
- W2073957993 countsByYear W20739579932023 @default.
- W2073957993 crossrefType "journal-article" @default.
- W2073957993 hasAuthorship W2073957993A5004391315 @default.
- W2073957993 hasAuthorship W2073957993A5016329638 @default.
- W2073957993 hasAuthorship W2073957993A5047855284 @default.
- W2073957993 hasAuthorship W2073957993A5051495533 @default.
- W2073957993 hasAuthorship W2073957993A5054123780 @default.
- W2073957993 hasAuthorship W2073957993A5070354722 @default.
- W2073957993 hasConcept C113196181 @default.
- W2073957993 hasConcept C120665830 @default.
- W2073957993 hasConcept C121332964 @default.
- W2073957993 hasConcept C127413603 @default.