Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073972116> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2073972116 endingPage "1666" @default.
- W2073972116 startingPage "1659" @default.
- W2073972116 abstract "Die cyclischen Enin-ketone 7a und 7b werden dargestellt und in die entsprechenden cyclischen Dieninyl-triflate 8a–c übergeführt. Die homologen Triflate 8a und 8b solvolysieren sowohl in Trifluorethanol als auch in Ethanol unter praktisch quantitativer Umlagerung über die intermediären Arylkationen 9a bzw. 9b zu den Arylethern. 26a, b bzw. 28a, b und unter innerer Ionenpaar-Rückkehr zu den Aryltriflaten 27a, b. Nach Zusatz von Bromid-Ionen werden auch die Arylbromide 30a, b erhalten. Synthesis and Solvolysis of Cyclic Dienynyl Triflates The cyclic enyne ketones 7a and 7b are prepared and converted into the corresponding cyclic dienynyl triflates 8a–c. The homologous triflates 8a and 8b solvolyse in trifluoroethanol as well as in ethanol with practically quantitative rearrangement via the intermediate aryl cations 9a and 9b to form the aryl ethers 26a, b and 28a, b, resp., and also with internal ion pair return to the aryl triflates 27a, b. The aryl bromides 30a, b are obtained by the addition of bromide ions." @default.
- W2073972116 created "2016-06-24" @default.
- W2073972116 creator A5046580795 @default.
- W2073972116 creator A5077685384 @default.
- W2073972116 date "1987-10-01" @default.
- W2073972116 modified "2023-09-27" @default.
- W2073972116 title "Synthese und Solvolyse cyclischer Dieninyl‐triflate" @default.
- W2073972116 cites W1965955442 @default.
- W2073972116 cites W1977416364 @default.
- W2073972116 cites W1984667152 @default.
- W2073972116 cites W1989540452 @default.
- W2073972116 cites W2002853033 @default.
- W2073972116 cites W2006445806 @default.
- W2073972116 cites W2015555480 @default.
- W2073972116 cites W2026768611 @default.
- W2073972116 cites W2157804198 @default.
- W2073972116 cites W2319084417 @default.
- W2073972116 cites W2329205386 @default.
- W2073972116 cites W4239127330 @default.
- W2073972116 doi "https://doi.org/10.1002/cber.19871201009" @default.
- W2073972116 hasPublicationYear "1987" @default.
- W2073972116 type Work @default.
- W2073972116 sameAs 2073972116 @default.
- W2073972116 citedByCount "14" @default.
- W2073972116 countsByYear W20739721162012 @default.
- W2073972116 countsByYear W20739721162013 @default.
- W2073972116 countsByYear W20739721162017 @default.
- W2073972116 crossrefType "journal-article" @default.
- W2073972116 hasAuthorship W2073972116A5046580795 @default.
- W2073972116 hasAuthorship W2073972116A5077685384 @default.
- W2073972116 hasConcept C155647269 @default.
- W2073972116 hasConcept C161790260 @default.
- W2073972116 hasConcept C178790620 @default.
- W2073972116 hasConcept C185592680 @default.
- W2073972116 hasConcept C188027245 @default.
- W2073972116 hasConcept C21774173 @default.
- W2073972116 hasConcept C2776300020 @default.
- W2073972116 hasConcept C2777738585 @default.
- W2073972116 hasConcept C2779293432 @default.
- W2073972116 hasConcept C2780263894 @default.
- W2073972116 hasConcept C2781076698 @default.
- W2073972116 hasConcept C71240020 @default.
- W2073972116 hasConcept C94412978 @default.
- W2073972116 hasConceptScore W2073972116C155647269 @default.
- W2073972116 hasConceptScore W2073972116C161790260 @default.
- W2073972116 hasConceptScore W2073972116C178790620 @default.
- W2073972116 hasConceptScore W2073972116C185592680 @default.
- W2073972116 hasConceptScore W2073972116C188027245 @default.
- W2073972116 hasConceptScore W2073972116C21774173 @default.
- W2073972116 hasConceptScore W2073972116C2776300020 @default.
- W2073972116 hasConceptScore W2073972116C2777738585 @default.
- W2073972116 hasConceptScore W2073972116C2779293432 @default.
- W2073972116 hasConceptScore W2073972116C2780263894 @default.
- W2073972116 hasConceptScore W2073972116C2781076698 @default.
- W2073972116 hasConceptScore W2073972116C71240020 @default.
- W2073972116 hasConceptScore W2073972116C94412978 @default.
- W2073972116 hasIssue "10" @default.
- W2073972116 hasLocation W20739721161 @default.
- W2073972116 hasOpenAccess W2073972116 @default.
- W2073972116 hasPrimaryLocation W20739721161 @default.
- W2073972116 hasRelatedWork W1973785063 @default.
- W2073972116 hasRelatedWork W1984919548 @default.
- W2073972116 hasRelatedWork W2013099987 @default.
- W2073972116 hasRelatedWork W2041642660 @default.
- W2073972116 hasRelatedWork W2069480498 @default.
- W2073972116 hasRelatedWork W2082982594 @default.
- W2073972116 hasRelatedWork W2316442989 @default.
- W2073972116 hasRelatedWork W2324898221 @default.
- W2073972116 hasRelatedWork W2952508841 @default.
- W2073972116 hasRelatedWork W2967800957 @default.
- W2073972116 hasVolume "120" @default.
- W2073972116 isParatext "false" @default.
- W2073972116 isRetracted "false" @default.
- W2073972116 magId "2073972116" @default.
- W2073972116 workType "article" @default.