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• W2073976325 abstract "A first step in the thermal degradation of polystyrene prepared by radical polymerisation has been isolated by heating the polymer in the temperature range 199–280°C. In this step a chain scission process occurs without formation of volatile products, involving, on average, about one bond between structural units in every 10 000. This gives more direct evidence than hitherto of the presence of ‘weak links’ in polystyrene which are shown to be randomly distributed in the polymer chains, their scission resulting in a single break in the molecule of polystyrene to which they belong. The very low energy of activation for chain scission suggests that more than one rate determining step is involved in the process." @default.
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• W2073976325 date "1981-05-01" @default.
• W2073976325 modified "2023-09-27" @default.
• W2073976325 title "‘Weak links’ in polystyrene" @default.
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• W2073976325 doi "https://doi.org/10.1016/0141-3910(81)90034-3" @default.
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