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- W2074005220 abstract "Thermolysis of 2-acetoxy-5,5-dimethyl-2-methylthio-Δ 3 -1,3,4-oxadiazoline in benzene at 110 °C afforded S-methyl 2-oxopropanethioate (S-methyl thiopyruvate) from 1,2-acyl migration in acetoxy(methylthio)carbene, as well as S,S-dimethyl 2-acetoxy-2-methylpropanebis(thioate) and S-methyl 2-acetoxy-2-(methylthio)butanethioate. The latter two, both composed of two carbene units, are derived from reaction of the first product with the carbene.Key words: acetoxy(methylthio)carbene, carbene, S-methyl thiopyruvate, rearrangement." @default.
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- W2074005220 date "2005-09-01" @default.
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- W2074005220 title "Reactions of acetoxy(methylthio)carbene and S-methyl thiopyruvate" @default.
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- W2074005220 doi "https://doi.org/10.1139/v05-151" @default.
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