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- W2074023489 abstract "Abstract Raman scattering experiments on K 2 Pt(CN) 4 Br 0.3 · 3H 2 O are reported between 5 and 300 K as a function of temperature. A line of A 1 symmetry detected at 44 cm −1 shows interesting temperature dependent properties. It is concluded from a comparison of the frequency, symmetry, and scattering intensity of this line with theoretical predictions that the excitation concerned represents the amplitude mode of the charge density wave (the line observed in infrared absorption being the phase mode). No Peierls transition is observed, but the results are consistent with a Peierls distortion present at all temperatures. The findings are correlated with inelastic neutron scattering and infrared studies. Finally, the CN stretching modes at 2189 and 2173 cm −1 and the water mode at 3490 cm −1 are studied as a function of temperature." @default.
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- W2074023489 date "1975-12-01" @default.
- W2074023489 modified "2023-09-24" @default.
- W2074023489 title "Raman scattering in K2Pt(CN)4Br0.3 · 3H2O" @default.
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- W2074023489 doi "https://doi.org/10.1016/0038-1098(75)90623-7" @default.
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