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- W2074036476 startingPage "3398" @default.
- W2074036476 abstract "A series of mono and binuclear cyanodithioformate (cdf) complexes with [RuIICpL2] [L = PPh3, AsPh3, SbPh3, (dppe)1/2, (dppm)1/2], exploiting its different coordination modes have been synthesized. Various physical and electrochemical methods have been used to characterize them. cdf by virtue of its vacant π* orbital introduces a low laying energy state in the compounds that facilitates Ru → cdf (dπ → π*) MLCT transition. MLCT band, upon dimerizaion shows red shift, whose magnitude depends upon site of attachment of second ruthenium moiety [, 3750 cm−1 for μ(η1–S; η1–S′) and 1010 cm−1 for μ(η1–S; η1–N) cdf complexes]. All complexes exhibit anodic oxidation peaks except binuclear μ(η1–S, η1–S′) cdf complex which exhibits reversible oxidation wave E1/2, −0.20 V vs. SCE in acetonitrite. Their spectral and electrochemical behavior are correlated with the σ, π characterstics of cdf and ruthenium moieties." @default.
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- W2074036476 date "1992-12-01" @default.
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- W2074036476 title "Cyanodithioformate Complexes of Cyclopentadientylruthenium(II). Synthesis, Spectral and Electrochemical Study" @default.
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- W2074036476 doi "https://doi.org/10.1246/bcsj.65.3398" @default.
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