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• W2074037195 abstract "The room-temperature reactions of closo-exo-4,5-[(μ-H)2Li(TMEDA)]-1-Li(TMEDA)-2,3-(SiMe3)2-2,3-C2B4H4 with anhydrous LnCl3 (Ln = Sm, Gd, Dy, Ho, Er), in molar ratios of 2:1 in dry benzene (C6H6), produced the sandwich paramagnetic species [Li(TMEDA)2][1-Cl-1-(μ-Cl)-2,2‘,3,3‘-(SiMe3)4-5,6-[(μ-H)2Li(TMEDA)]-4,4‘,5‘-[(μ-Η)3Li(TMEDA)]-1,1‘-commo-Ln(2,3-C2B4H4)2] (Ln = Sm (1), Gd (2), Dy (3), Ho (4), Er (5)) in yields of 65%, 88%, 71%, 90%, and 93%, respectively. The compounds were characterized by IR spectroscopy, magnetic susceptibility measurements, and single-crystal X-ray diffraction studies. Compounds 2 and 3 were further characterized by EPR spectroscopy, and compound 1 was also characterized by 1H, 13C, 11B, and 7Li NMR spectroscopy. All compounds are bent-sandwich complexes in which a Ln(III) atom is coordinated to two carborane ligands and two chloride ions. The room-temperature magnetic susceptibilities of 1−4 were found to be 1.1, 7.3, 9.4, and 10.1 μB per metal atom, respectively." @default.
• W2074037195 created "2016-06-24" @default.
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• W2074037195 date "1996-02-06" @default.
• W2074037195 modified "2023-10-16" @default.
• W2074037195 title "Chemistry of <i>C</i>-Trimethylsilyl-Substituted Heterocarboranes. 20. Synthetic and Structural Studies on Sandwich Ln(III) Carborane Clusters. II (Ln(III) = Sm, Gd, Dy, Ho, Er)" @default.
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• W2074037195 doi "https://doi.org/10.1021/om950780y" @default.
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