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- W2074070534 abstract "Earlier infrared spectral studies of cellulose nitrates (CEN) having different degrees of substitution, and of a number of model compounds, in the range of the OH- and CH-valence oscillation frequencies [1], had given some correlations of the absorption bands. The work reported here deals with the infrared spectral study of CEN solutions with different degrees of esterification; this was made to obtain details of the type of intra- and intermolecular reactions, and about their effects on the structural properties of CEN. There are several reports of the study results on CEN solutions by infrared spectroscopy [2–4], such as that on the reaction of CEN with CO(CH 3 ) 2 , (C 2 H 5 ) 2 O+ +C 2 H 5 OH, and with some of the plasticizer types. The authors established that CEN formed intermolecular H-bonds with the examined types of solvent. The spectra of the CEN solutions were also used to determine the number of nitro-ether groups [5, 6]. There are, unfortunately, few studies dealing with spectra of CEN solutions as a means of structural analysis, or of the conformational characteristics, of this important polymer." @default.
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- W2074070534 date "1970-01-01" @default.
- W2074070534 modified "2023-09-26" @default.
- W2074070534 title "Infrared spectroscopic study of cellulose nitrate solutions" @default.
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- W2074070534 doi "https://doi.org/10.1016/0032-3950(70)90316-3" @default.
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