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• W2074095938 abstract "In the present paper, the liquid-liquid micro extraction of 4-tert-butylphenol from aque- ous solution to trioctyl phosphate organic phase in carbon paste electrode was studied by potenti- ometry and semi-empirical quantum chemistry with MOPAC2009. The extraction dynamic process was monitored by open circuit potential method, which follows an exponential association function with the apparent first extraction kinetic rate constant of 0.01685 s � 1 . The Nernstian plot of poten- tial difference of the open circuit potentials against logarithm of 4-tert-butylphenol concentration at 500 s extraction time gives a slope of 0.01382, and indicates that 3 or 4 of 4-tert-butylphenol mol- ecules can be extracted by one cluster of trioctyl phosphate dimer. This equation can also serve as working curve for the determination of 4-tert-butylphenol in the concentration range of 1.0 · 10 � 4 - 5.0 · 10 � 7 M with detection limit of 5.0 · 10 � 7 M( n = 3, ratio of signal/noise = 3). The semi- empirical quantum chemical calculation offers a thermodynamic evidence for the molecular mech- anism of the liquid-liquid micro extraction of 4-tert-butylphenol from aqueous solution to trioctyl phosphate cluster." @default.
• W2074095938 created "2016-06-24" @default.
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• W2074095938 date "2017-05-01" @default.
• W2074095938 modified "2023-10-18" @default.
• W2074095938 title "Potentiometric and semi-empirical quantum chemical studies on liquid–liquid micro-extraction of 4-tert-butylphenol with trioctyl phosphate clusters" @default.
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• W2074095938 doi "https://doi.org/10.1016/j.arabjc.2014.05.012" @default.
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