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- W2074144279 abstract "A d- olivosyl donor in which the C(3) and C(4) hydroxyls are both protected by an extremely bulky group, t-BuPh2Si, undergoes aryl C-glycosidation in an α-selective manner, and the product configuration remains unchanged under various Lewis acid conditions. The features are rationalized by the ring flipping of the pyranoside ring (1C4) in the glycosyl donor and the C-glycoside product, due to the severe repulsion of the siloxy groups." @default.
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- W2074144279 date "1996-01-01" @default.
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- W2074144279 title "On the stereochemistry of aryl C-glycosides: Unusual behavior of bis-TBDPS protected aryl C-olivosides" @default.
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- W2074144279 doi "https://doi.org/10.1016/0040-4039(95)02227-9" @default.
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