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- W2074162004 abstract "A new mesoporous polymer constituting of Fe(III)-poly-(p-phenylenediamine) (Fe-MPPD) has been synthesized by using the supramolecular assembly of anionic surfactant sodium dodecylsulphate (SDS) as template under mild conditions. The polymeric framework resulted via simultaneous oxidative polymerization of p-phenylenediamine (PPD) and cross-linking in the presence of Fe(III) ion using water as reaction medium. Upon removal of template SDS molecules through solvent extraction this material has retained the 2D-hexagonal nanostructure. The presence of Fe(III) in the polymeric material has been confirmed by atomic absorption spectroscopy (AAS, 18.3 and 10.2 wt% for two samples) and 57Fe Mössbauer spectroscopy. The temperature dependence of zero-field cooled magnetization showed spin freezing temperature at 3.5 K, below which there is a large coercivity due to significant contribution of surface anisotropy. The porosity and the magnetic property of the material are found to be dependent on the molar ratio Fe(III):PPD and SDA content." @default.
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- W2074162004 date "2011-07-01" @default.
- W2074162004 modified "2023-09-28" @default.
- W2074162004 title "Fe(III)-containing mesoporous poly-(p-phenylenediamine): Synthesis, characterization and magnetic properties" @default.
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- W2074162004 doi "https://doi.org/10.1016/j.micromeso.2010.12.048" @default.
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