Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074163553> ?p ?o ?g. }
- W2074163553 endingPage "216" @default.
- W2074163553 startingPage "208" @default.
- W2074163553 abstract "Conducting poly-1-naphthol films (0.5–2.0 μm) showed a decreasing tendency for doping with film thickness. The average specific capacitance of poly-1-naphthol films formed by cyclic voltammetry in MeCN containing tetrabutylammonium perchlorate in the reduced dedoped state was found to be ∼ 10 mF cm−3 and increased on electrochemical oxidation (doping) to ∼ 60 mF cm−3. Stabilization of the polymer by repetitive cyclic voltammetry led to increase or decrease in the redox charge with number of cycles, depending on the final oxidation potential and in all cases, the peak separation decreased due to rearrangement of the polymer chains. The polymer doping/dedoping processes showed a pronounced increase in the diffusion coefficient of the charge transfer with thickness and a substantial difference between the doping and dedoping process. The doping process is controlled by an initial fast charge propagation step and followed by a slower step of anion insertion into the polymer film while in the dedoping only the anion removal from the film could be distinguished. The electron transfer for the redox [Fe(CN)6]4−/3− on the polymer films showed also a strong dependence on film thickness. It is inferred that the polymer film is composed of two layers; an inner compact layer (< 1 μm) which impedes to a larger extent the charge transfer reactions and an outer less compact and easily removable layer with more facile permeability. When the film is thickened, however, the inner layer is partially distorted and its barrier character towards charge transfer is gradually lost." @default.
- W2074163553 created "2016-06-24" @default.
- W2074163553 creator A5069730500 @default.
- W2074163553 date "1997-11-01" @default.
- W2074163553 modified "2023-10-11" @default.
- W2074163553 title "Stability and behavior of poly-1-naphthol films towards charge transfer reactions" @default.
- W2074163553 cites W1480755644 @default.
- W2074163553 cites W1491991973 @default.
- W2074163553 cites W1492024981 @default.
- W2074163553 cites W1512882873 @default.
- W2074163553 cites W1528937357 @default.
- W2074163553 cites W1568976366 @default.
- W2074163553 cites W1583500596 @default.
- W2074163553 cites W1850241744 @default.
- W2074163553 cites W1966534911 @default.
- W2074163553 cites W1967152364 @default.
- W2074163553 cites W1968523049 @default.
- W2074163553 cites W1979225430 @default.
- W2074163553 cites W2018669767 @default.
- W2074163553 cites W2019961133 @default.
- W2074163553 cites W2025590493 @default.
- W2074163553 cites W2028110248 @default.
- W2074163553 cites W2028960561 @default.
- W2074163553 cites W2034915527 @default.
- W2074163553 cites W2035938900 @default.
- W2074163553 cites W2044968661 @default.
- W2074163553 cites W2045453093 @default.
- W2074163553 cites W2045671996 @default.
- W2074163553 cites W2046816437 @default.
- W2074163553 cites W2056690088 @default.
- W2074163553 cites W2064735901 @default.
- W2074163553 cites W2067792638 @default.
- W2074163553 cites W2068733423 @default.
- W2074163553 cites W2077839673 @default.
- W2074163553 cites W2081303933 @default.
- W2074163553 cites W2085038759 @default.
- W2074163553 cites W2087800468 @default.
- W2074163553 cites W2093835273 @default.
- W2074163553 cites W2126164913 @default.
- W2074163553 cites W2129689095 @default.
- W2074163553 cites W2504294252 @default.
- W2074163553 doi "https://doi.org/10.1016/s0040-6090(97)00355-6" @default.
- W2074163553 hasPublicationYear "1997" @default.
- W2074163553 type Work @default.
- W2074163553 sameAs 2074163553 @default.
- W2074163553 citedByCount "13" @default.
- W2074163553 countsByYear W20741635532012 @default.
- W2074163553 countsByYear W20741635532020 @default.
- W2074163553 crossrefType "journal-article" @default.
- W2074163553 hasAuthorship W2074163553A5069730500 @default.
- W2074163553 hasConcept C113196181 @default.
- W2074163553 hasConcept C127413603 @default.
- W2074163553 hasConcept C145148216 @default.
- W2074163553 hasConcept C147789679 @default.
- W2074163553 hasConcept C159985019 @default.
- W2074163553 hasConcept C17525397 @default.
- W2074163553 hasConcept C178790620 @default.
- W2074163553 hasConcept C179104552 @default.
- W2074163553 hasConcept C185592680 @default.
- W2074163553 hasConcept C192562407 @default.
- W2074163553 hasConcept C2777869211 @default.
- W2074163553 hasConcept C2780709120 @default.
- W2074163553 hasConcept C42360764 @default.
- W2074163553 hasConcept C49040817 @default.
- W2074163553 hasConcept C521977710 @default.
- W2074163553 hasConcept C52859227 @default.
- W2074163553 hasConcept C55904794 @default.
- W2074163553 hasConcept C57863236 @default.
- W2074163553 hasConceptScore W2074163553C113196181 @default.
- W2074163553 hasConceptScore W2074163553C127413603 @default.
- W2074163553 hasConceptScore W2074163553C145148216 @default.
- W2074163553 hasConceptScore W2074163553C147789679 @default.
- W2074163553 hasConceptScore W2074163553C159985019 @default.
- W2074163553 hasConceptScore W2074163553C17525397 @default.
- W2074163553 hasConceptScore W2074163553C178790620 @default.
- W2074163553 hasConceptScore W2074163553C179104552 @default.
- W2074163553 hasConceptScore W2074163553C185592680 @default.
- W2074163553 hasConceptScore W2074163553C192562407 @default.
- W2074163553 hasConceptScore W2074163553C2777869211 @default.
- W2074163553 hasConceptScore W2074163553C2780709120 @default.
- W2074163553 hasConceptScore W2074163553C42360764 @default.
- W2074163553 hasConceptScore W2074163553C49040817 @default.
- W2074163553 hasConceptScore W2074163553C521977710 @default.
- W2074163553 hasConceptScore W2074163553C52859227 @default.
- W2074163553 hasConceptScore W2074163553C55904794 @default.
- W2074163553 hasConceptScore W2074163553C57863236 @default.
- W2074163553 hasIssue "1-2" @default.
- W2074163553 hasLocation W20741635531 @default.
- W2074163553 hasOpenAccess W2074163553 @default.
- W2074163553 hasPrimaryLocation W20741635531 @default.
- W2074163553 hasRelatedWork W1975791743 @default.
- W2074163553 hasRelatedWork W1995700372 @default.
- W2074163553 hasRelatedWork W2018266715 @default.
- W2074163553 hasRelatedWork W2026652747 @default.
- W2074163553 hasRelatedWork W2039440331 @default.
- W2074163553 hasRelatedWork W2046008188 @default.
- W2074163553 hasRelatedWork W2084810032 @default.
- W2074163553 hasRelatedWork W2375389133 @default.