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- W2074201214 abstract "The primary carbopalladation intermediate resulting under Heck conditions from bicyclopropylidene and phenyl iodide in the presence of tris(α-furyl)phosphane rearranges to give a π-allylpalladium complex which is efficiently trapped by various nucleophiles RnXH. This rearrangement leads to substituted methylenecyclopropanes in good to excellent yields (42–99 %) [Eq. (1); X=C (n=3), N (n=2), O (n=1)]. The intermediate 1,1-dimethyleneallylpalladium complex was isolated and fully characterized by an X-ray crystal-structure analysis." @default.
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- W2074201214 date "2001-09-17" @default.
- W2074201214 modified "2023-10-15" @default.
- W2074201214 title "Nucleophilic Trapping of π-Allylpalladium Intermediates Generated by Carbopalladation of Bicyclopropylidene: A Novel Three-Component Reaction" @default.
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- W2074201214 doi "https://doi.org/10.1002/1521-3773(20010917)40:18<3411::aid-anie3411>3.0.co;2-d" @default.
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