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• W2074225114 abstract "Abstract The corrosion at 600–800 °C of two iron-based alloys containing 15 and 30 wt% yttrium in H2H2S mixtures under 10−8 atm S2 was studied to establish whether yttrium additions can improve the sulfidation resistance of pure Fe. The presence of yttrium is beneficial, but not as much as expected. The corrosion rate of iron is considerably reduced by the yttrium addition, but the two alloys still corrode much more rapidly than pure yttrium. The sulfidation kinetics of pure yttrium are rather irregular, while the corrosion rate of pure iron and the two alloys tends to become parabolic after an initial period of variable length. Under all conditions the two alloys form an external FeS layer, overlying an intermediate region of complex composition containing a mixture of the compounds of the two metals and an innermost region of internal attack. Iron can still diffuse through the intermediate region to form the outer FeS layer with non-negligible rate. The scaling behavior of these alloys is discussed by taking into account the presence of intermetallic FeY compounds and the limited solubility of yttrium in iron." @default.
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• W2074225114 date "1997-06-01" @default.
• W2074225114 modified "2023-09-27" @default.
• W2074225114 title "The sulfidation of Fe-15 wt%Y and Fe-30 wt%Y in H 2 H 2 S mixtures at 600–800 °C" @default.
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• W2074225114 doi "https://doi.org/10.1016/s0010-938x(97)00017-6" @default.
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