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- W2074243775 abstract "Herein we describe a novel Co2(CO)8-catalyzed intramolecular aza-Pauson−Khand-type reaction of alkynecarbodiimide derivatives affords pyrrolo[2,3-b]indol-2-one ring systems in reasonable yields. This is the first reported Co2(CO)8 successfully applied in the hetero-Pauson−Khand reaction. Significantly, the transformation of one of our pyrrolo[2,3-b]indol-2-one derivatives into the indole alkaloid, (±)-physostigmine, was completed in a highly stereoselective manner." @default.
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- W2074243775 date "2005-12-08" @default.
- W2074243775 modified "2023-10-03" @default.
- W2074243775 title "Co<sub>2</sub>(CO)<sub>8</sub>-Catalyzed Intramolecular Hetero-Pauson−Khand Reaction of Alkynecarbodiimide: Synthesis of (±)-Physostigmine" @default.
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- W2074243775 doi "https://doi.org/10.1021/ol052562z" @default.
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