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- W2074244906 abstract "The thermal reaction of Rh(acac)(CO)2 with alkenes has been studied both in the absence and in the presence of high-pressure hydrogen using in situ FTIR and polymer matrix techniques. A series of rhodium alkenes complexes, Rh(acac)(CO)(alkene) (alkene=ethene, propene, 1-butene, 1-octene and trans-3-octene), have been characterized using IR spectroscopy. In the presence of a high-pressure hydrogen, catalytic hydrogenation of alkenes was achieved using Rh(acac)(CO)2 within the polyethylene matrix. These results suggest that this hydrogenation process follows the so-called “olefin route” operating via a sequence of ligand loss, binding of an alkene, oxidative addition of hydrogen to the rhodium metal centre, insertion of the coordinated alkene into the MH bond and finally reductive elimination of the alkane. Rh(acac)(CO) appears to be the active catalytic species in this process. High-pressure polymer matrix techniques have allowed us to unravel some of the interconversions of the catalytic species involved in this catalytic process." @default.
- W2074244906 created "2016-06-24" @default.
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- W2074244906 date "2003-07-01" @default.
- W2074244906 modified "2023-10-16" @default.
- W2074244906 title "Study of the reaction of Rh(acac)(CO)2 with alkenes in polyethylene films under high-pressure hydrogen and the Rh-catalysed hydrogenation of alkenes" @default.
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- W2074244906 doi "https://doi.org/10.1016/s0022-328x(03)00439-x" @default.
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