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- W2074301008 abstract "Abstract Thermodynamic properties of solid benzene and furan are investigated through Swenson's equaiotn of state. It is found that those two solids, in their dynamic disordered state, behave like cubic crystals from the thermodynamic point of view. In particular, this means that the crystal lattice configuration remains constant at constant volume, which is supported by previous high pressure low frequency Raman measurements. This behaviour seems to be restricted to the reorientationally disordered phases. The relations between thermodynamics, local crystal configuration and dynamic disorder in molecular crystals is discussed in terms of atom-atom pair wise potentials, Frenkel's model of molecular reorientations between discrete wells and the rotational diffusion model." @default.
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- W2074301008 date "1979-01-01" @default.
- W2074301008 modified "2023-10-03" @default.
- W2074301008 title "Thermodynamics of Molecular Reorientationally Disordered Phases at High Pressure" @default.
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- W2074301008 doi "https://doi.org/10.1080/15421407908084416" @default.
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