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• W2074306997 abstract "The gas-phase electron affinities of fluorene, biphenyl, its 2-methyl, 2.2′-, 3.3′- and 4.4′-dimethyl derivatives has been measured by means of ETS. The different dihedral angle between the two rings in the various compounds is reflected in the splitting between the in-phase and out-of-phase combinations of the benzene e2u (π*) empty orbitals. In the planar fluorene, the electron affinities of the π* orbitals arising from the benzene e2u orbitals with a node at the attached carbon atoms indicate a sizeable through-space interaction and a very small net electronic effect of the CH2 bridge." @default.
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• W2074306997 date "1983-12-01" @default.
• W2074306997 modified "2023-09-24" @default.
• W2074306997 title "Application of electron transmission spectroscopy to conformational studies: Electron affinities of methyl-substituted biphenyls" @default.
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• W2074306997 doi "https://doi.org/10.1016/0301-0104(83)85253-7" @default.
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