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- W2074310462 abstract "The spirobi(benzodioxaphosphole) system stabilizes high phosphorus coordination. Thus bis(o-phenylenedioxy)chlorophosphorane adds pyridine in a fast first step without dissociation to a neutral, and in a slower second step to a cationic hexacoordinate phosphorus species. The equilibria compositions were determined by 31 P NMR. The cation of the bis(pyridine) adduct can be isolated as the stable crystalline chloride which partly decomposes on dissolving. More stable, even in boiling water, is the cation of the 2,2′-bipyridine adduct. 1 H NMR studies of the bis(pyridine) adduct lead to a cis structure. A δ 31 P comparison for hexacoordinate spirobi(benzodioxaphospholes) is given." @default.
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- W2074310462 date "1976-08-01" @default.
- W2074310462 modified "2023-10-03" @default.
- W2074310462 title "Vier- und fünfgliedrige Phosphorheterocyclen, XIV Kationen des hexakoordinierten Phosphors." @default.
- W2074310462 doi "https://doi.org/10.1515/znb-1976-0812" @default.
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