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• W2074316435 abstract "Solutions of lithium hexafluroantimonate, LiSbF6, dissolved in diethylene glycol dimethyl ether (diglyme), CH3O(CH2CH2O)2CH3, are used as a model for high molecular weight poly(ethylene oxide), PEO, complexed with LiSbF6. During this work, a 2:1 diglyme:LiSbF6 crystal was discovered and its structure solved by single-crystal X-ray diffraction techniques. The compound crystallizes in the orthorhombic Pccn space group with Z = 4. In this crystal, the lithium ion is 6-fold coordinated by two diglyme molecules, while the anions are isolated. Raman and FTIR vibrational spectroscopy were used to study both the crystal and a series of diglyme−LiSbF6 solutions. Similarities in modes sensitive to molecular conformation show that the local conformational structure in the crystal also occurs in diglyme−LiSbF6 solutions." @default.
• W2074316435 created "2016-06-24" @default.
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• W2074316435 date "2004-05-25" @default.
• W2074316435 modified "2023-09-23" @default.
• W2074316435 title "Characterization of Crystalline and Solution Phases of Diglyme−LiSbF₆" @default.
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• W2074316435 doi "https://doi.org/10.1021/jp031128g" @default.
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