FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074328101> ?p ?o ?g. }

• W2074328101 endingPage "66" @default.
• W2074328101 startingPage "55" @default.
• W2074328101 abstract "Abstract— Kinetic resonance Raman (RR) experiments were designed to study the time-behaviour of the retinal-binding protein bacteriorhodopsin (BR) in its photochemical cycle. The unphotolyzed chro-mophore B-570 and the two intermediates L-550 and M-412 were probed by the characteristic C=C stretching vibrations of the retinal moiety. Time resolution was achieved with a spinning cell as flow system in combination with two CW lasers in a pump-probe configuration. RR spectra were probed at 475 nm at various delay times between pump and probe event. The deconvolution of the spectra into the various components B-570, L-550 and M-412 was carried out by curve fitting procedures. It was found that at pH7.4 L-550 decays — with a time-constant of 62 μs — not completely but to a residual level of 35% of its initial value. This intermediate L-amplitude finally disappears in the ms-range (4.5 ms) synchroneously with the intermediate M-412. An analogeous time-behaviour was found at pH 4.6. In the basic range also an “L” -intermediate could be identified which is coupled to the long-lived M-component. To explain the peculiar time-dependence it is proposed that during the fast decay of L a dynamic equilibrium between L and M is established. Then during the reconstitution of B-570 the two intermediates disappear synchroneously. A molecular model is presented in which the dynamic equilibrium between L and M is explained by an oscillatory motion of a proton from the Schiff base group of the chromophore to its counterion." @default.
• W2074328101 created "2016-06-24" @default.
• W2074328101 creator A5031085575 @default.
• W2074328101 creator A5076907899 @default.
• W2074328101 date "1986-01-01" @default.
• W2074328101 modified "2023-09-23" @default.
• W2074328101 title "TIME-RESOLVED RESONANCE RAMAN STUDIES ON THE PHOTOCHEMICAL CYCLE OF BACTERIORHODOPSIN" @default.
• W2074328101 cites W105684836 @default.
• W2074328101 cites W140801292 @default.
• W2074328101 cites W1486421713 @default.
• W2074328101 cites W1488717803 @default.
• W2074328101 cites W187856331 @default.
• W2074328101 cites W1971557054 @default.
• W2074328101 cites W1973334425 @default.
• W2074328101 cites W1987747767 @default.
• W2074328101 cites W1995000064 @default.
• W2074328101 cites W1995139556 @default.
• W2074328101 cites W1997894837 @default.
• W2074328101 cites W2002129248 @default.
• W2074328101 cites W2004575479 @default.
• W2074328101 cites W2004755637 @default.
• W2074328101 cites W2007727191 @default.
• W2074328101 cites W2012702663 @default.
• W2074328101 cites W2013820324 @default.
• W2074328101 cites W2016237935 @default.
• W2074328101 cites W2023281801 @default.
• W2074328101 cites W2023490737 @default.
• W2074328101 cites W2031474615 @default.
• W2074328101 cites W2033616067 @default.
• W2074328101 cites W2042398961 @default.
• W2074328101 cites W2054878552 @default.
• W2074328101 cites W2057876340 @default.
• W2074328101 cites W2058484603 @default.
• W2074328101 cites W2070750491 @default.
• W2074328101 cites W2070784586 @default.
• W2074328101 cites W2073511782 @default.
• W2074328101 cites W2078723552 @default.
• W2074328101 cites W2079710746 @default.
• W2074328101 cites W2082875390 @default.
• W2074328101 cites W2084567281 @default.
• W2074328101 cites W2089929012 @default.
• W2074328101 cites W2107577050 @default.
• W2074328101 cites W2580317798 @default.
• W2074328101 doi "https://doi.org/10.1111/j.1751-1097.1986.tb05591.x" @default.
• W2074328101 hasPublicationYear "1986" @default.
• W2074328101 type Work @default.
• W2074328101 sameAs 2074328101 @default.
• W2074328101 citedByCount "50" @default.
• W2074328101 countsByYear W20743281012019 @default.
• W2074328101 countsByYear W20743281012021 @default.
• W2074328101 crossrefType "journal-article" @default.
• W2074328101 hasAuthorship W2074328101A5031085575 @default.
• W2074328101 hasAuthorship W2074328101A5076907899 @default.
• W2074328101 hasConcept C113196181 @default.
• W2074328101 hasConcept C119599485 @default.
• W2074328101 hasConcept C120665830 @default.
• W2074328101 hasConcept C121332964 @default.
• W2074328101 hasConcept C127413603 @default.
• W2074328101 hasConcept C1276947 @default.
• W2074328101 hasConcept C135889238 @default.
• W2074328101 hasConcept C139210041 @default.
• W2074328101 hasConcept C184779094 @default.
• W2074328101 hasConcept C185592680 @default.
• W2074328101 hasConcept C189542057 @default.
• W2074328101 hasConcept C2776509742 @default.
• W2074328101 hasConcept C2776568683 @default.
• W2074328101 hasConcept C2778113554 @default.
• W2074328101 hasConcept C40003534 @default.
• W2074328101 hasConcept C41625074 @default.
• W2074328101 hasConcept C43617362 @default.
• W2074328101 hasConcept C46141821 @default.
• W2074328101 hasConcept C4839761 @default.
• W2074328101 hasConcept C54516573 @default.
• W2074328101 hasConcept C55493867 @default.
• W2074328101 hasConcept C62520636 @default.
• W2074328101 hasConcept C71240020 @default.
• W2074328101 hasConcept C75473681 @default.
• W2074328101 hasConcept C81370116 @default.
• W2074328101 hasConceptScore W2074328101C113196181 @default.
• W2074328101 hasConceptScore W2074328101C119599485 @default.
• W2074328101 hasConceptScore W2074328101C120665830 @default.
• W2074328101 hasConceptScore W2074328101C121332964 @default.
• W2074328101 hasConceptScore W2074328101C127413603 @default.
• W2074328101 hasConceptScore W2074328101C1276947 @default.
• W2074328101 hasConceptScore W2074328101C135889238 @default.
• W2074328101 hasConceptScore W2074328101C139210041 @default.
• W2074328101 hasConceptScore W2074328101C184779094 @default.
• W2074328101 hasConceptScore W2074328101C185592680 @default.
• W2074328101 hasConceptScore W2074328101C189542057 @default.
• W2074328101 hasConceptScore W2074328101C2776509742 @default.
• W2074328101 hasConceptScore W2074328101C2776568683 @default.
• W2074328101 hasConceptScore W2074328101C2778113554 @default.
• W2074328101 hasConceptScore W2074328101C40003534 @default.
• W2074328101 hasConceptScore W2074328101C41625074 @default.
• W2074328101 hasConceptScore W2074328101C43617362 @default.
• W2074328101 hasConceptScore W2074328101C46141821 @default.
• W2074328101 hasConceptScore W2074328101C4839761 @default.
• W2074328101 hasConceptScore W2074328101C54516573 @default.

• next